亚洲av日韩精品一区二区久久,優質欧美成人爽爽爽视频,国产亚洲欧美日韩精品一区二区三区 http://www.owweac.cn/fr Sat, 14 Sep 2024 07:27:50 +0000 F RFR toutes les heures 1 https://wordpress.org/?v=6.5.5 http://www.owweac.cn/wp-content/uploads/2020/04/Meetyou-Carbide-Logo.svg Carbure de Meetyou http://www.owweac.cn/fr 32 32 209719448 Study on the Erosion-Wear Performance of YG8 carbide http://www.owweac.cn/fr/erosion-wear-performance-of-yg8-carbide/ http://www.owweac.cn/fr/erosion-wear-performance-of-yg8-carbide/#respond Sat, 14 Sep 2024 02:50:30 +0000 http://www.owweac.cn/?p=22830 In recent years,YG8 tungsten carbide (WC) materials have gained increasing attention due to their excellent wear resistance, corrosion resistance, and high-temperature oxidation resistance. This paper uses a self-made shock wave-driven gas-solid two-phase flow erosion-wear experimental device to study the erosion-wear characteristics of carbide YG8 under various conditions and to reveal its erosion-wear mechanisms.

 

Erosion-Wear Experimental Materials and Equipment

Experimental Materials

Tungsten carbide (WC) carbide?is a composite material produced using powder metallurgy techniques, with WC, a metal carbide that is difficult to dissolve, as the matrix and a binder added. It is characterized by high hardness and strong wear resistance. The WC carbide?used in this experiment is YG8, which is employed as the coating material for the valve core and outlet sleeve in coal direct liquefaction devices. YG8 is a tungsten-cobalt carbide?with a cobalt binder, a density of 14.6 g/cm3, a hardness of HV 1350, an elastic modulus of 540 MPa, a bending strength of 1500 MPa, and a compressive strength of 4470 MPa.

The experiment uses quartz sand (SiO?) particles as the erosion particles, which are commonly used in erosion-wear tests. The particles are sieved to achieve an average particle size of 150 μm, as shown in Figure 1.

Study on the Erosion-Wear Performance of YG8 carbide 7

Experimental Equipment

The experiment uses a self-made shock wave-driven gas-solid two-phase flow erosion-wear testing device. This device primarily consists of a shock wave generator, a velocity measurement system, a high-speed camera, a heating system, and a temperature control system.

Study on the Erosion-Wear Performance of YG8 carbide 8

In this setup, nitrogen gas is connected to the driving section to generate shock waves with a specific Mach number. The driving section and the driven section are separated by an aluminum film. Experimental particles are placed on a tin foil located between the driven section and the accelerating section. By adjusting the pressure relief valve, gas is introduced into the driving section of the shock tube. When the pressure difference across the film reaches a critical value, the film ruptures suddenly, generating a shock wave. The high-speed gas flow then propels the solid particles through the accelerating section to the desired experimental velocity. Upon impacting the specimen surface, the high-speed particles cause material loss, thus facilitating the erosion process.

The driving section, driven section, and accelerating section are each equipped with dynamic pressure sensors, charge amplifiers, and dynamic test analyzers to measure shock wave velocity. A high-speed camera in the experimental section captures the particle motion trajectories. The specimen holder is equipped with a temperature heating system and a temperature control system, allowing for adjustment to the required experimental temperature.

 

Erosion-Wear Experimental Parameters and Methods

Experimental Parameters

The impact angle, denoted as θ (see Figure 3), is defined as the angle between the axis of the shock tube and the surface of the specimen being eroded (0°to 90°). The desired impact angle is achieved by rotating the specimen holder.

The impact distance L is the distance between the center of the shock tube’s outlet and the center of the specimen’s surface. Typically, L is set between 30 and 50 mm during experiments. When conducting experiments at different impact angles, the position of the shock tube needs to be adjusted to maintain a consistent impact distance.

Study on the Erosion-Wear Performance of YG8 carbide 9

In the experiment, the impact velocity is adjusted by changing the thickness of the aluminum foil. Aluminum foils with thicknesses of 0.13 mm, 0.20 mm, and 0.30 mm are used for the erosion-wear tests. A high-speed camera is employed to record the particle trajectories. By analyzing these trajectories, the particle velocity v p is determined.

Study on the Erosion-Wear Performance of YG8 carbide 10

In the equation, ΔI represents the distance between the ends of the particle clusters in consecutive frames, measured in meters; Δn is the number of frames between measurements; and f is the filming frequency, measured in frames per second (FPS).

Using the high-speed camera, the velocity of 150 μm SiO? particles is tested. By replacing aluminum foils of different thicknesses, the corresponding membrane rupture pressure ratios are obtained, which in turn allows for the determination of the impact velocity. The velocities corresponding to different aluminum foil thicknesses are summarized in Table 1. The specific calculation method for particle velocity can be found in the referenced literature.

Study on the Erosion-Wear Performance of YG8 carbide 11

Experimental Method

Before the experiment, the nickel-based carbide specimens are first polished using 1000# sandpaper. The specimens are then cleaned with an ultrasonic cleaner, air-dried, and weighed to obtain an average value. The specimens are fixed onto the specimen holder, and the angle of the specimen and the distance between the shock tube and the specimen are adjusted. The temperature control system is activated, and the experimental temperature is set. Aluminum foils of the appropriate thickness are selected and solid particles are loaded simultaneously.

The lighting is turned on, and the dynamic testing analyzer and high-speed camera are activated. The camera lens height is adjusted so that the distance from the shock tube outlet to the specimen surface is within the field of view of the high-speed camera. The nitrogen gas valve is then opened to start the experiment. When the aluminum foil ruptures, the valve is immediately closed, and the high-speed camera captures the particle trajectories during the experiment.

At the end of the experiment, the specimen is cooled, cleaned, and dried. The specimen is weighed 10 times using an electronic balance to record the average weight. The erosion-wear rate is then calculated using equation (2).

Study on the Erosion-Wear Performance of YG8 carbide 12

In the equation, E represents the erosion-wear rate, measured in mg/g; Δm is the mass loss of the material, measured in mg; and m p is the mass of a single impact particle, measured in grams.

 

Analysis and Discussion of Erosion-Wear Experimental Results

Effect of Impact Angle on YG8 Wear Rate

Under an impact velocity of 175 m/s, the erosion-wear rates of the specimens were measured by varying the impact angles, as shown in Figure 4.?YG8

From Figure 4, it can be observed that the erosion-wear rate of the specimen initially increases and then decreases as the impact angle increases. The erosion-wear rate reaches its peak at an impact angle of 75°. The experimental results indicate that YG8 is a typical brittle material, with the maximum erosion-wear rate occurring at high impact angles. The erosion-wear characteristics of YG8 are consistent with the behavior of brittle materials, where the erosion-wear rate varies with the impact angle.

 

Impact Angle on Coating Erosion-Wear Performance

Particle velocity is a crucial factor affecting the wear rate of materials. Impact experiments were conducted on specimens at impact angles of 30°, 60°, and 90° under three different impact velocities: 148 m/s, 175 m/s, and 200 m/s. The relationship between erosion-wear rate and particle impact velocity is shown.

Figure 5 demonstrates that, at all three impact angles, the erosion-wear rate of the material increases with increasing impact velocity. There is a critical impact velocity at which erosion-wear begins, related to the abrasive properties and the material’s characteristics. Erosion-wear occurs only when the velocity exceeds this critical value. Extensive erosion tests indicate that the erosion-wear rate has the following relationship with particle velocity:

E=kv” (3)

where

v is the particle velocity in m/s;

k is a constant; and

n is the velocity index. A higher

n value indicates that the erosion-wear rate of the material is more influenced by the particle impact velocity.

Fitting the experimental data to equation (3) yields velocity indices of 2.34, 2.27, and 2.28 for impact angles of 30°, 60°, and 90°, respectively, for YG8 material.

 

Analysis of Erosion-Wear Mechanisms

Analysis of the erosion-wear morphology of specimens at an impact angle of 90° reveals that the erosion-wear is primarily driven by the impact forces of the solid particles directly striking the composite layer. Due to the high brittleness of both tungsten carbide particles and the composite layer matrix, high-velocity solid particle impacts more readily induce plastic deformation or crack formation, leading to the development of pits and cracks.

During the erosion process, the abrasive quartz sand continuously impacts the surface, creating numerous pits. The edges of these pits accumulate material that has been deformed and squeezed out, forming a lip-like flange. With continued particle impacts, this flange is progressively eroded and stripped away due to repeated compression. The wear mechanism can be summarized as erosion-induced compression leading to pit formation and material detachment.

As the reinforcement phase, WC particles have much higher hardness and stiffness compared to quartz sand, which helps them better withstand the abrasive impacts. During the erosion-wear process, the coating undergoes cutting and plowing effects from the sharp edges of the abrasive particles, resulting in plastic deformation, progressive fatigue, and delamination. The protruding WC particles bear the brunt of the abrasive impact. Table 2 shows the elemental chemical composition of the specimen surface before and after the erosion experiments.

 

Conclusion

As the impact angle increases, the erosion-wear rate of YG8 material first increases and then decreases, reaching a maximum at an impact angle of 75°. YG8 exhibits the erosion-wear characteristics typical of brittle materials.

At impact angles of 30°, 60°, and 90°, the erosion-wear rate of YG8 material increases with rising impact velocity. The corresponding velocity indices, obtained from fitting the erosion-wear rate versus velocity relationship, are 2.34, 2.27, and 2.28, respectively.

The primary erosion-wear mechanism for YG8 material involves the formation of pits and microcracks on the material surface due to high-angle impacts. These features are caused by the detachment of Co and WC particles from the matrix and the development of microcracks under high-velocity impacts.

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Application of WC-Ni carbide?in Mechanical Seal Face Materials http://www.owweac.cn/fr/mechanical-seal/ http://www.owweac.cn/fr/mechanical-seal/#respond Fri, 13 Sep 2024 09:14:31 +0000 http://www.owweac.cn/?p=22821 A mechanical seal is a device that relies on elastic components to pre-tighten the sealing faces of the static and rotating rings, and uses the pressure of the medium combined with the pressure of the elastic components to achieve axial balance, thus ensuring axial face sealing. Figure 1 shows a common type of mechanical seal structure. In the sealing area, the rotating ring and the stationary ring’s faces slide relative to each other. Due to the combined effects of heat, chemicals, physical forces, and mechanical factors, these contact surfaces are most prone to leakage or even damage. The operational condition of the sealing rings determines the performance and lifespan of the mechanical seal, and the performance of the sealing ring materials directly affects its operational condition. Therefore, understanding the performance requirements of sealing materials for mechanical seals and selecting appropriate sealing materials are crucial for ensuring the safe operation of mechanical seals.

 

Requirements for Seal Face Materials in Mechanical Seals

To ensure the proper operation of sealing rings in mechanical seal devices, they are typically configured as a pair consisting of a hard ring and a soft ring with different hardness levels, considering aspects such as wear reduction, corrosion resistance, and prevention of galling. During operation, the sealing rings may come into contact and generate friction when starting, stopping, or experiencing fluctuations in working conditions. Therefore, the material for the hard ring needs to have sufficient strength, rigidity, wear resistance, and thermal conductivity. Friction and fluid shear forces can elevate the temperature of the sealing rings, so the sealing material must exhibit good thermal conductivity, heat resistance, and thermal shock resistance. To ensure a long service life, the sealing ring must also have good corrosion resistance. Additionally, the hard ring should possess good formability and machinability, low density and permeability, and excellent self-lubricating properties. No single material can fully meet all these requirements, so typically, the main performance criteria for sealing materials are defined based on the operating environment, and suitable materials are selected accordingly.

mechanical seal ring

Application of WC-Ni carbide as Mechanical Seal Materials

To ensure the longevity and stable operation of mechanical seal materials, the sliding materials should have appropriate thermal compatibility and thermal conductivity, as well as suitable coefficients of thermal expansion, elastic modulus, and friction factors. WC-Ni carbides are known for their excellent performance in mechanical seals, making them suitable for applications in high-pressure, high-speed, high-temperature, corrosive environments, and media containing solid particles.

Application of WC-Ni carbide?in Mechanical Seal Face Materials 17

Characteristics of WC-Ni carbide

Since the introduction of carbides in the 1920s, cobalt has been regarded as the best binder phase and continues to play a significant role in the preparation of carbides. With the rapid advancement of science and technology, the applications of carbides have expanded, leading to a surge in demand. Due to the scarcity of cobalt resources, scientists worldwide have prioritized cobalt as a strategic material and have been researching ways to reduce or substitute cobalt in carbides. Nickel, being close to cobalt in the periodic table, with similar density, melting point, and atomic radius, can effectively wet and support the hard phase and has lower radioactivity compared to cobalt, making it a common substitute.

The characteristics of WC-Ni and WC-Co carbides during the sintering process are similar. However, due to the different strengthening effects of Ni and Co on the hard phase, WC-Ni may exhibit slightly lower performance in certain aspects compared to WC-Co carbides. By adding a small amount of metal elements to enhance the binder phase, using fine low-carbon WC particles, and employing vacuum sintering processes, WC-Ni carbides with lower porosity and a uniform, fine-grained structure can be achieved. Their hardness, bending strength, and tribological properties can meet or exceed those of WC-Co carbides, while their corrosion resistance is also significantly improved. Additionally, as Ni replaces the radioactive element Co, it provides good radiation protection when used under radioactive conditions. By carefully controlling the total carbon content and grain size of the alloy, and adding appropriate amounts of Mo and Cr, WC-Ni carbides can be produced with non-magnetic properties and excellent physical and mechanical performance, thereby mitigating the effects of special working conditions and environmental factors.

Application of WC-Ni carbide?in Mechanical Seal Face Materials 18

Physical and Mechanical Properties of WC-Ni carbide for Mechanical Seals

WC-Ni carbides are made by mixing WC and Ni powders in a specific ratio, adding a binder, and then pressing and sintering the mixture. With a melting point of approximately 2700°C, WC particles are primarily bonded together during the sintering process through the melting of Ni. At high temperatures, some WC dissolves into Ni, forming a WC-Ni eutectic with a lower melting point than Ni. Consequently, the sintering temperature varies with changes in Ni content and WC grain size. For composite materials, physical parameters such as elastic modulus, coefficient of thermal expansion, Poisson’s ratio, thermal diffusivity, and thermal conductivity can vary based on the proportion and distribution of each phase.

Application of WC-Ni carbide Materials in Mechanical Seals

Due to their exceptional toughness, rigidity, high hardness, good wear resistance, high bending strength, and high thermal conductivity, both WC-Ni and WC-Co carbides are notable. WC-Ni carbides offer superior corrosion resistance compared to WC-Co alloys and do not emit radiation under neutron exposure, making them suitable for use in mechanical seals operating under high pressure, high speed, high temperature, corrosive media, media containing solid particles, and radioactive environments. Currently, WC-Ni carbides have significant application value in vehicle transmission shaft seals, power shift transmissions, pumps in special operating conditions, and rotary seals for aircraft, as well as in the petrochemical industry and nuclear power seals.

Influence of Microstructure on the Properties of WC-Ni carbides

Application of WC-Ni carbide?in Mechanical Seal Face Materials 19

The unevenness in microstructure can adversely affect the strength of carbides. Minor variations in the binder phase content and distribution, WC grain size, carbon content, and any form of impurity contamination can lead to an uneven microstructure that negatively impacts the mechanical properties of WC-Ni carbides.

Influence of WC Grain Size on the Properties of WC-Ni carbides

WC-Ni carbides use Ni as the binder metal. During the sintering process, Ni melts at the sintering temperature and bonds the WC particles together into a solid mass. These alloys exhibit very high hardness, are difficult to machine, and possess excellent wear resistance. Variations in the processing methods can lead to significant differences in the alloy’s composition and properties, and the morphology of the WC grains can also affect the performance of WC-Ni carbides.

3.2Changes in WC Grain Morphology During Liquid Phase Sintering of WC-Ni carbides

The coarseness of WC grains can significantly affect the bending strength of carbides, while uneven distribution of Ni can lead to brittle fracture of the alloy. To improve the fracture toughness of the product, it is essential to strengthen the interface between WC and the binder phase or to enhance the strength of the binder phase. Therefore, controlling the sintering process and conditions will impact the mechanical properties of WC-Ni carbides.

During sintering, the shape of WC grains in the carbide?is also influenced by shape relaxation and the grain growth process. The higher the ratio of the average intercept length of the binder phase (the average length of each grain intersected by any testing line on a cross-section) to the WC grain size, the less impact it has on the shape of the WC grains, resulting in a more equiaxed grain morphology.

Application of WC-Ni carbide?in Mechanical Seal Face Materials 20

Effect of Binder on Temperature Residual Stress in WC-Ni carbides

When the content of the metallic binder Ni in WC-Ni alloy materials is relatively high, the compressive stress in fine WC grains is greater than that in coarse grains. This is because, with a constant WC content, the average free path of the binder in fine powder is shorter than in coarse powder. When the WC-Ni alloy contains less binder, the difference in the average free path of the binder is minimal, and the variation in residual stress with temperature is not significant. Therefore, if conditions allow, the Ni content in WC-Ni alloy sealing rings should be reduced to minimize the uneven distribution of residual stress due to temperature changes, thus reducing or even preventing thermal cracking in the sealing rings.

Current Research Status on the Application Performance of WC-Ni carbides

?Corrosion Resistance of WC-Ni Alloys

Compared to WC-Co carbides, WC-Ni carbides exhibit superior wear resistance. This is due to the binder in WC-Ni alloys having excellent corrosion resistance, with both passivation and electrochemical corrosion rates for WC-Ni carbides being significantly lower than those for WC-Co carbides. Under acidic conditions in practical production processes, WC alloys with Ni as the binder show better acid resistance than those with Co as the binder.

Table 2 compares the corrosion resistance of WC-Ni and WC-Co carbides. The results show that substituting Co with Ni significantly enhances the corrosion resistance of WC carbides. However, the corrosion resistance of a material is specific to its alloy composition, grain size, and the corrosive conditions (including temperature, concentration, time, and corrosion state). For example, the corrosion resistance of YWN8 in 68%-90% HNO? is not significantly different from, and even slightly lower than, that of YG6 alloy. This is primarily due to the poor resistance of metallic Ni to strong oxidizing acids like HNO?; as the concentration of HNO? and the Ni content in the alloy increase, its corrosion resistance decreases.

Table 2 Corosion resistance performance comparison between WC-Ni and WC-Co cemented carbides

Tribological Performance of WC-Ni Alloy Mechanical Seal Rings

WC-Ni carbide?sealing rings exhibit excellent wear resistance. This is because WC-Ni carbides possess strong oxidation resistance and corrosion resistance in fluid sealing media, which contributes to their superior wear resistance. The friction coefficient of WC-Ni carbides is related to the content, grain size, and distribution of the binder phase. A softer binder phase can lead to adhesion during friction. Additionally, the content and composition of the binder phase can affect the hardness of WC-Ni, thereby influencing the wear resistance of the WC-Ni carbide.

 

Conclusion

Mechanical seal materials are a crucial area of research in sealing technology. With the advancement of modern science and technology and the increasing demands of production and daily life, the requirements for sealing technology have become more stringent. However, research in this field in our country is still relatively behind. Strengthening interdisciplinary collaboration and continually improving experimental and theoretical research are key to overcoming the technological barriers in mechanical seals imposed by foreign countries.

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?The 3 Impact of Coarse Tungsten Carbide Particle Size on WC-Co Alloy Grain Size http://www.owweac.cn/fr/the-impact-of-coarse-tungsten-carbide-particle-size/ http://www.owweac.cn/fr/the-impact-of-coarse-tungsten-carbide-particle-size/#respond Sat, 07 Sep 2024 02:56:05 +0000 http://www.owweac.cn/?p=22808 Coarse Tungsten Carbide (WC) is a fundamental raw material for producing coarse WC-Co alloys. The classic method for producing this tungsten carbide involves high-temperature reduction of tungsten oxide and high-temperature carburization. The Fischer particle size of tungsten carbide ranges from about 10 μm to over 20 μm. The coarser the particles, the higher the manufacturing cost. Choosing high-quality and cost-effective raw powder is an important consideration for many alloy and tool manufacturers. This study selects tungsten carbide powders with significantly different particle sizes and investigates the relationship between the characterization parameters of these powders and the grain size of the alloy. The aim is to provide insights that could help reduce energy and material consumption in the manufacture of coarse-grained alloys.

 

Experimental Methods

Raw Materials

The experiment uses coarse and extra-coarse WC powders from well-known suppliers, with their main characteristics shown in Table 1. Additionally, 2.0 μm cobalt powder from the same supplier was also used.

particle size

Experimental Methods

For the preparation of WC-10%Co (where all content is given in weight percentage), weigh 900 g of WC, 100 g of Co, and 20 g of PEG. Measure 235 mL of alcohol and 2000 g of grinding balls. Add these into a 2.4 L ball mill. The mill is operated at a speed of 63 r/min for 14.5 hours. After milling, the mixture is dried, sieved, and then pressed into samples weighing 10 g each. The samples are sintered in a continuous vacuum sintering furnace at 1450°C.

Particle Size Measurement

For coarse tungsten carbide, measure the Fischer particle size in both the as-supplied and milled states. The samples are resin-mounted and analyzed using a metallurgical microscope to determine the grain size and particle size distribution of the powder. The alloy grain size and particle size distribution are measured using classic metallographic methods, and the coercive force of the samples is also assessed.

 

 

Results and Analysis

Fischer Particle Size (Fsss) and Alloy Grain Size

As-Supplied Particle Size and Alloy Grain Size

The metallographic images of alloys made from WC powders #1 and #2 are shown in Figures 1 and 2, respectively. Comparing Figures 1 and 2, it can be observed that the WC grain size in Figure 2 appears to be slightly coarser than in Figure 1. This indicates that coarser as-supplied Fsss particle sizes of WC lead to coarser grain sizes in the WC-Co alloys. Metallographic analysis shows that the average WC grain sizes for alloys made from powders #1 and #2 are 4.8 μm and 5.8 μm, respectively. Thus, the average grain size of WC in sample #2 is 1.2 times that in sample #1. The as-supplied Fsss particle size of #2 WC powder is 2.5 times that of #1 WC powder. Clearly, there is no direct proportional relationship between the as-supplied Fsss particle size of WC powder and the alloy grain size. Additionally, the Fsss particle size values for #1 WC powder are 2.5 times the alloy grain size, and for #2 WC powder, it is 5.3 times the alloy grain size. This indicates that the as-supplied WC powders for both samples are primarily aggregated polycrystalline WC particles, with more severe agglomeration for coarser WC powders.

?The 3 Impact of Coarse Tungsten Carbide Particle Size on WC-Co Alloy Grain Size 26

?The 3 Impact of Coarse Tungsten Carbide Particle Size on WC-Co Alloy Grain Size 27

Milled La taille des particules and Alloy Grain Size

Comparing Table 1 with the metallographic grain sizes in Figures 1 and 2, it can be seen that the Fsss particle sizes of milled WC powders #1 and #2 are relatively close to the alloy grain sizes. Moreover, the measured alloy grain sizes are higher than the milled Fsss particle size values. This discrepancy is due to differences in measurement principles as well as grain growth during the sintering process. However, it clearly indicates that the Fsss particle sizes of coarse WC powders in the milled state are very close to the alloy grain sizes. The ratios of average grain sizes to milled particle sizes for alloys #1 and #2 are 1.15 and 1.31, respectively.

Raw Material WC Grain Size and Alloy Grain Size

Results from Direct Metallographic Measurement

Metallographic images of #1 and #2 WC powders after mounting and etching are shown in Figures 3 and 4. The grain sizes measured using metallographic methods are 5.31 μm and 8.5 μm, respectively. The grain size distributions of the powders and alloys are shown in Figures 5 and 6.

?The 3 Impact of Coarse Tungsten Carbide Particle Size on WC-Co Alloy Grain Size 28 ?The 3 Impact of Coarse Tungsten Carbide Particle Size on WC-Co Alloy Grain Size 29

Figures 3 and 4 clearly indicate that the grain size of #2 WC is significantly larger than that of #1 WC. This suggests that WC with a coarser as-supplied Fischer particle size also has coarser grains. Additionally, it is evident that #1 WC exhibits better dispersion, with less pronounced sintering between particles compared to #2 WC. The severe sintering in #2 WC particles is a major reason why the metallographic grain size is much larger than the alloy grain size, and also explains why the grains in #2 WC are much larger than those in #1 WC.

From the grain size distribution of the raw powders and alloys in Figures 5 and 6, it can be seen that sample #1 contains coarse WC grains of 15–20 μm in the raw material, which are not present in the alloy. In contrast, sample #2 has a substantial amount of WC grains in the 15–35 μm range, though only a small amount of 15–20 μm grains are found in the alloy. This suggests that the severe sintering of the mounted WC, although difficult to distinguish by metallographic methods after etching, was fragmented during the intense grinding process.

Moreover, comparing the WC and alloy grain size distributions in Figures 5 and 6 shows that the grain size distribution of WC in sample #1 is more consistent with the alloy grain distribution than in sample #2. This consistency is a significant reason why many researchers believe that WC similar to sample #1 is more conducive to producing coarse alloys with a more uniform grain size.

WC Particle Size and Alloy Coercive Force

The coercive forces of the alloys made from #1 and #2 powders are 4.6 kA/m and 4.3 kA/m, respectively. The relationship between the WC-Co alloy grain size and the alloy’s coercive force can be expressed using the empirical formula (1).

?The 3 Impact of Coarse Tungsten Carbide Particle Size on WC-Co Alloy Grain Size 30

In the formula:

  • Hc= coercive force of the alloy (kA/m)
  • Com= cobalt content in the alloy (%)
  • Dwc= average WC grain size in the alloy (μm)

 

According to the calculations, the average grain sizes of alloys #1 and #2 are 7.4 μm and 8.8 μm, respectively. Clearly, the calculated grain sizes are significantly larger than the measured grain sizes, but the difference between the average grain sizes of alloys #2 and #1 is close to the difference observed using metallographic methods. The results obtained from formula (1) do not show a clear quantitative relationship with the Fsss particle sizes of the raw WC in both states, but the size of the raw material particles can still be used to predict the alloy grain size and coercive force.

Conclusions

Based on the above, the following conclusions can be drawn:

1.Coarse WC powders with larger as-supplied Fsss particle sizes tend to have higher milled Fsss particle sizes and larger grain sizes, leading to alloys with larger grain sizes.

2.The Fsss particle size in the milled state of coarse WC can be used to evaluate the grain size of coarse WC and predict the grain size of WC-Co alloys. Under the test conditions, the alloy grain size is 1.1 to 1.3 times the Fsss particle size of the milled WC.

3.Coarse WC powders with as-supplied Fsss particle sizes around 10 μm have a better consistency in grain size distribution with the alloy WC grain size distribution compared to extremely coarse WC powders with Fsss particle sizes above 25 μm.

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The 3 Elements You Should Take into Consideration when You Select End Mills http://www.owweac.cn/fr/select-end-mill/ http://www.owweac.cn/fr/select-end-mill/#comments Sat, 07 Sep 2024 01:48:36 +0000 http://www.owweac.cn/?p=22796 When a user has the option between a replaceable insert end mill and a solid carbide end mill (hereafter referred to as “solid carbide end mill”), they typically ask a fundamental question: which tool offers better performance? In which machining fields does each tool have more advantages? Rather than being a question of which is superior, it is more about which is better suited to specific applications. Understanding the distinct performance characteristics of each type of tool and how to use them effectively to achieve good machining results is essential.

Generally, compared to traditional insert end mills, solid carbide end mills offer significantly higher machining precision. This fact holds true specifically for the performance of the tool during cutting operations. Although both types of tools may have the same dimensional precision grade, the rigidity of solid carbide material is much higher than that of a steel tool holder with insert blades. This means that solid carbide end bit mills are less likely to undergo deflection or deformation under cutting forces, leading to higher machining precision.

The 3 Elements You Should Take into Consideration when You Select End Mills 37

Base Material of Solid Carbide End Mills

The machining performance of solid carbide end mills largely depends on the type of carbide base material used. The base material is crucial because it must support the cutting edges of the tool, endure significant cutting forces, and prevent any form of tool damage.

To ensure that end mills have sufficient toughness and provide good dynamic resistance, solid carbide end mills typically use micro-grain carbide as the base material (see Figure 2). This base material offers higher hardness and better edge sharpness while maintaining good toughness. However, compared to conventional grain-sized carbide, micro-grain carbide has relatively poorer thermal conductivity (its ability to dissipate heat from the cutting area). This means that heat generated during cutting tends to remain on the tool surface. Therefore, the cutting edges of solid carbide end mills must be able to withstand this cutting heat and manage the contact arc length, which is an important consideration when selecting solid carbide end mills.

The 3 Elements You Should Take into Consideration when You Select End Mills 38

Coating and Cutting Edge Preparation of Solid Carbide End Mills

To enhance tool wear resistance and isolate the cutting zone, which generates heat, from the tool base (since heat accumulation in the base material can shorten tool life), solid carbide end mills are typically coated. Additionally, because the cutting edges of solid carbide end bit mills are quite sharp, appropriate adhesion between the tool base and the coating is also crucial (see Figure 3). This is especially important for smaller diameter solid carbide end mills, where the sharpness of the cutting edges is a key factor in the tool’s machining performance.

The 3 Elements You Should Take into Consideration when You Select End Mills 39

The Ideal Cutting Edge for Solid Carbide End Mills

The ideal cutting edge of a solid carbide end mill should have as high a hardness as possible while minimizing the risk of chipping. This goal can be partially achieved through proper cutting edge preparation. Generally, different solid carbide end mills may employ various cutting edge preparation methods, edge geometries, and sharpness levels depending on the required machining quality and tool life.

 

The cutting edge is the intersection line between the tool’s rake face and flank face. By grinding these faces, a sharp cutting edge can be obtained. However, if a PVD coating is deposited directly on a sharp cutting edge, it can create high internal stresses within the coating. These high internal stresses can cause the coating to crack and peel off during cutting, thereby shortening the tool’s life. The quality and effectiveness of the coating depend on its ability to withstand and/or reduce the wear rate during cutting. To ensure that the coating adheres more firmly to the cutting edge and to prevent edge damage, it is necessary to perform edge reinforcement (or blunting) treatment (see Figure 4). In other words, to ensure machining stability and achieve coating functionality, a certain degree of edge sharpness must be sacrificed, which in turn extends tool life.

The 3 Elements You Should Take into Consideration when You Select End Mills 40

It can even be said that the importance of cutting edge preparation for solid carbide end bit mills outweighs that of base material type and coating technology. Logically, this has a significant impact on the regrinding of solid carbide end mills. After regrinding, if the cutting edge is not re-blunted to restore its initial condition, the full potential of the tool repair cannot be realized. Therefore, considering the high initial cost of solid carbide end mills, it is crucial for the original tool manufacturer or its qualified service centers to handle tool regrinding services.

The 3 Elements You Should Take into Consideration when You Select End Mills 41

Machining Strategies for Solid Carbide End Mills

Solid carbide end mills can be categorized into several major types based on their size and geometry, and further subdivided into many specialized subcategories according to different machining ranges. In various tool application areas, design features such as flute geometry, cutting edge angles, rake and relief angles, and helix angles play crucial roles in differentiating among the types of solid carbide end bit mills. This classification guides the selection of both end mills and machining strategies.

So, which machining strategy is the best choice? This depends on the overall machining goals: is your primary aim to maximize productivity and part output, or to minimize tool costs and simplify tool types? Additionally, it also depends on the workpiece and various related factors: is the tool used for slotting, side milling, or a combination of both?

A final consideration is constraints, such as: what is the potential machining capability of the machine tool? How rigid is the workpiece clamping? These factors might become limiting constraints, preventing the use of more advanced machining strategies or more efficient specialized solid carbide end mills.

The correct choice of solid carbide end bit mill depends on multiple factors, with the most important being the adoption of the correct machining strategy. In practice, many constraints cannot be changed: the machining machine, CAM system, and the material, size, tolerance, and shape of the workpiece are fixed constants. However, within the existing machining system framework, machining results can still be influenced by formulating the right machining strategy and using various methods, and by optimizing cutting conditions through adjustments to feed rate, cutting speed, and cutting depth according to the overall machining goals.

Based on the selected focus and technical strategy, appropriate solid carbide end mills can be chosen. There are two obvious ways to select tools:

  1. Performance-Based Selection:Choose specialized end mills with specific applications (such as side milling, slotting, or 3D profiling) to achieve optimal performance.
  2. Versatility-Based Selection:Choose general-purpose end bit mills with a wider range of applications but fewer types.

Regardless of the selection method, users need to further narrow down the options within the available varieties and specifications of solid carbide end mills.

The 3 Elements You Should Take into Consideration when You Select End Mills 42

 

Sommaire

The material, size, tolerance, and shape of the machined parts are given constants. However, within the existing machining system framework, machining results can still be influenced by formulating the correct machining strategy and employing various methods. Additionally, cutting conditions can be optimized by adjusting feed rate, cutting speed, and cutting depth according to the overall machining goals.

Based on the chosen focus and technical strategy, appropriate solid carbide end mills can be selected. There are two clear approaches to tool selection:

  1. Performance-Based Selection:Choose specialized end mills designed for specific applications (such as side milling, slotting, or 3D profiling) to achieve the best performance.
  2. Versatility-Based Selection:Choose general-purpose end mills that, while fewer in types, offer a wider range of applications.

Regardless of the selection method, users need to further narrow down the choices within the available varieties and specifications of solid carbide end mills.

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How to Treat Tool Build-Up in Aluminum Alloy Cutting Processes Using Chemical Methods? http://www.owweac.cn/fr/how-to-treat-tool-build-up/ http://www.owweac.cn/fr/how-to-treat-tool-build-up/#comments Fri, 30 Aug 2024 05:43:56 +0000 http://www.owweac.cn/?p=22789 To reduce tool Build-Up and minimize the cost of tool wear during mass production, a combined theoretical and practical analysis approach is employed. This approach comprehensively examines the processing conditions, including processing efficiency, cooling methods, and material properties. It aims to address the issue of aluminum adhesion caused by aluminum melting, allowing for tool reuse and thus lowering tool consumption costs.

With the rapid development of China’s automotive industry, especially in the booming new energy vehicle sector, lightweighting has become a core topic. The key to lightweighting is changing traditional materials. Aluminum alloys, with their high strength and low weight, are essential for achieving vehicle lightweighting. The complex geometric shapes of automotive parts and the increasing proportion of die-cast aluminum alloy parts in vehicles have led to a growing demand for CNC machining of die-cast parts.

CNC machining of aluminum alloy automotive parts requires high efficiency, stable continuous production, and decreasing costs, necessitating more detailed control and planning of the entire production process.

How to Treat Tool Build-Up in Aluminum Alloy Cutting Processes Using Chemical Methods? 45

Tool Build-Up

Aluminum’s inherent property of low melting point causes it to become “sticky” during cutting. Due to this characteristic and inadequate cooling in actual conditions, the heat generated by friction during the microscopic cutting process cannot be released in time or effectively. This results in aluminum melting and adhering to the tool’s cutting edges and chip flutes. Upon cooling, the aluminum solidifies and sticks to the tool, forming build-up. This phenomenon, commonly referred to in the industry as “easy tool sticking,” leads to tool failure.

Tools are consumables in CNC machining processes and represent a significant cost component. Generally, cutting tools for aluminum alloys need to be sharper, with chip flutes specially polished and coated with aluminum-specific coatings to improve chip removal efficiency. The automotive industry’s push for high efficiency increases feed rates and cutting speeds, which raises the heat generated during cutting and the risk of aluminum melting and sticking to the tool, thereby increasing costs due to tool failure from build-up.

With environmental regulations, minimal quantity lubrication (MQL) is widely used as a cutting fluid alternative in aluminum alloy CNC machining. However, the low melting point of aluminum exacerbates the reduced cooling effect of MQL, further promoting build-up. Tools that fail due to sticking account for about 40% of conventional tool failures. Traditional methods of dealing with build-up, such as tapping or striking, rarely restore tools for reuse. Thus, a new solution is proposed.

Treatment Measures

The new solution involves the following steps:

  1. Remove the tool with build-up.
  2. Obtain solid NaOH, dilute it with water, and place it in a ceramic container.
  3. Once diluted into NaOH solution, immerse the tool with aluminum build-up in the solution. Ensure that the build-up areas are fully submerged and maintain immersion for 2 hours, or adjust based on practical conditions. Table 1 compares traditional and new treatment methods.
Traditional Treatment New Solution
Tools with aluminum build-up are discarded directly, leading to significant production costs Immersion liquid can remove aluminum from complex and irregular shapes
Physical methods like tapping and striking damage the polished surface, leading to tool discard or reduced cutting efficiency Short treatment time and simple operation
Short treatment time and simple operation Easy-to-obtain treatment materials with low cost

 Build-Up

Chemical Principles

Using A1Si7Mg material commonly found in automotive parts as an example, where A1 content is approximately 93.5%, Si content is 6.5%, and Mg content is 0.25%. Both Al and Si react with NaOH solution. Immersion in NaOH solution removes the primary A1 component from the tool. The principle involves the reaction between metal and NaOH, producing bubbles (H?), which eventually causes the adhered aluminum to detach.

Chemical reaction equations are as follows:

  1. Si reacts with NaOH: Si + 2NaOH + H?O → Na?SiO? + 2H?↑
  2. Al reacts with NaOH: 2Al + 2NaOH + 2H?O → 2NaAlO? + 3H?↑

The final result is the removal of aluminum, making the tool reusable.

Experimental Validation for Reducing Build-up

The theoretical method was tested using a tap. Taps are valuable tools in aluminum alloy machining, requiring a longer lifespan and featuring complex geometric shapes. Once aluminum adhesion occurs, physical removal is nearly impossible, making this test more significant and representative.

Due to high heat generated during machining and possible inadequate cooling, aluminum melts instantly and adheres to the flutes rendering the tap unusable due to damaged threads.

The test involved immersing the tap with aluminum build-up in NaOH solution.

The test conclusion: The tap, after complete immersion in NaOH, showed that the build-up had completely detached. Residual aluminum slag was found in the test container. The treated tap was used for further machining, and the workpiece threads met the required specifications. The tap was successfully restored for reuse.

How to Treat Tool Build-Up in Aluminum Alloy Cutting Processes Using Chemical Methods? 46

Conclusion

The automotive parts industry, characterized by mass production, requires extensive cutting validation during the initial equipment and tool design phase. Common issues such as build-up during validation due to parameter mismatches, equipment adjustments, and operator experience can significantly increase trial costs and production cycles. This method effectively addresses build-up issues, greatly reducing tool costs and processing time, extending tool life, and substantially lowering production costs.

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How to Select End Milling Cutter Shapes for Machining Hardened Steel Mold Cavities? http://www.owweac.cn/fr/end-milling-cutters-shape/ http://www.owweac.cn/fr/end-milling-cutters-shape/#respond Fri, 23 Aug 2024 08:20:48 +0000 http://www.owweac.cn/?p=22776 It is essential to carefully select the appropriate end milling blade shapes for hardened steel mold cavities. High-speed cutting has emerged as one of the top ten mold manufacturing technologies in recent years, introducing a new approach to mold processing. Among these technologies, high-speed machining of hardened steel has gained significant attention. Solid carbide tools are commonly used for rough and finish machining of mold cavities, with a focus on improving processing efficiency during rough and semi-finish machining. General-purpose end mills, such as ball-end mills and corner radius end mills, perform well under favorable conditions with small cutting parameters but may suffer from severe wear, chipping, or even breakage of the cutting edge under high feed rates, large cutting widths, and small cutting depths typical in the mold industry. Modern mold production demands that tools achieve maximum metal removal rates under high-speed machining conditions to improve efficiency, with much of the research focusing on cutting technology. This paper discusses the optimization of tool blade design to enhance performance and meet the requirements for high-efficiency machining.

Conventional end mills have the following drawbacks under high-efficiency cutting conditions:

1.To reduce cutting forces and facilitate chip evacuation, the end edges of corner radius end mills typically feature a concave design with a high edge at the tip and a low center. This means that only the tip participates in cutting during face milling, resulting in high stress and a tendency for chipping.

2.The cutting edge of ball-end mills exhibits both negative rake angles and low-speed cutting inefficiencies, leading to a low metal removal rate.

3.Cutting forces are primarily radial, with the main cutting forces directed along the X and Y axes, causing tool chatter under high-efficiency cutting conditions.

To address these issues, the tool’s end edge shape is optimized by incorporating an arc design for edge protection. The concave straight edge is replaced with an arc edge where the tip is lower and the center is higher. The benefits include:

1.Increased cutting edge length, reducing the cutting load per unit, and distributing the cutting allowance and cutting force across the entire edge shape.

2.The bottom arc design, with a larger radius and smaller main cutting angle, reduces cutting forces and cutting-induced vibrations.

End Mill Cutter Shape Design and Analysis

Taking a φ10 four-flute end milling cutter as an example, the optimized arc-shaped milling cutter blade outperforms conventional end mills (corner radius and ball-end mills) in terms of effective cutting edge shape and length Le (black thick line) at the same cutting depth (0.5mm), as shown in Figure 1 and Table 1. The arc-shaped milling cutter has the longest effective cutting edge length, followed by the ball-end milling cutter, with the corner radius end milling cutter having the shortest. To comprehensively evaluate the performance of arc-shaped milling cutters compared to conventional end mills under high-efficiency machining conditions, both cutting simulations and cutting experiments were conducted for comparison.

How to Select End Milling Cutter Shapes for Machining Hardened Steel Mold Cavities? 54

How to Select End Milling Cutter Shapes for Machining Hardened Steel Mold Cavities? 55

During the cutting simulation, both the end milling cutter and the workpiece were simplified and precisely configured to ensure accurate calculations. A 10mm section of the end mill was selected as the simulation cutting portion, with detailed settings applied only to the cutting edge area. The total rotation angle of the tool during simulation was set to 190°, ensuring complete data for tool entry and exit points. The cutting parameters were set based on relatively large values commonly used in the mold industry: vc= 120m/min,fz=0. 4mm /z,ap = 0. 5mm,ae =10mm. The workpiece material selected was hardened steel (SKD11, with a hardness of HRC58), and the tool material chosen was carbide. The milling method used was climb milling. The cutting simulation model and the cutting conditions are shown in Figure 2.

How to Select End Milling Cutter Shapes for Machining Hardened Steel Mold Cavities? 56

 

Comparison of Cutting Forces

Cutting force is a crucial indicator of cutting performance. Excessive cutting force significantly impacts tool life. The cutting forces in the X, Y, and Z directions were directly extracted using the AdvantEdge post-processing program, showing how cutting forces fluctuate over time (see Figure 3).

end milling cutter performance

From the figure, it is evident that the corner radius end milling cutter exhibits relatively stable cutting behavior. In contrast, the ball-end mill shows significant fluctuations in cutting force. This instability is attributed to the ball-end mill’s two-flute connection at the center, where long and short teeth alternate during milling. The variation in the number of active cutting edges leads to changes in the effective cutting edge length, resulting in substantial fluctuations in cutting force. The optimized arc-shaped end milling cutter initially encounters a larger cutting allowance when it begins to engage with the workpiece, resulting in higher cutting forces. As the cutting progresses deeper into the workpiece, the cutting allowance is uniformly removed radially along the tool, causing the cutting force to decrease and stabilize.

Comprehensive Comparison

The average values of the simulated cutting forces and cutting temperatures were calculated (see Table 1). It can be observed that the ball-end mill operates at a lower cutting temperature but experiences greater fluctuations in cutting force. The corner radius end milling cutter, with its shorter effective cutting edge, generates smaller cutting forces. The optimized arc-shaped end milling cutter produces higher cutting forces, predominantly in the axial direction.

Since the cutting edges involved in the process are concentrated on the end edges, they can be considered as simultaneously engaged in cutting. The resultant cutting force ftotalf_{total}ftotal? and the cutting force in the axial plane fxyf_{xy}fxy? per unit length of the cutting edge are shown in Table 2. The corner radius end mill exhibits the highest cutting force per unit length, indicating that under these conditions, the tool’s cutting edge experiences a higher cutting load, making it more prone to chipping and cutting vibrations. The optimized arc-shaped end milling cutter has the lowest cutting force per unit length, suggesting a more reasonable distribution of the cutting load.

How to Select End Milling Cutter Shapes for Machining Hardened Steel Mold Cavities? 57

Cutting Experiment Analysis

To comprehensively evaluate the cutting performance of the tools, the experiment was conducted to verify both cutting force and tool durability.

The experimental material, SKD11 with a hardness of HRC61, was the same as that used in the cutting simulation. The machining was performed on a MIKRON UCP1000 machining center using climb milling and dry cutting. The cutting process and parameters were consistent with those used in the cutting simulation.

How to Select End Milling Cutter Shapes for Machining Hardened Steel Mold Cavities? 58

Cutting Force Experiment

The cutting force sensor used was a Swiss Kistler 9265B three-component piezoelectric dynamometer, along with a charge amplifier and a corresponding data acquisition and processing system. After filtering, the cutting force values are shown in Table 3. The results indicate that the optimized arc-shaped end milling cutter generates a larger overall cutting force, but the cutting load per unit length is the smallest, consistent with the conclusions drawn from the cutting force simulation.

How to Select End Milling Cutter Shapes for Machining Hardened Steel Mold Cavities? 59

Cutting Performance Experiment for End Milling Cutter

Cutting hardened steel typically results in significant tool wear and short tool life, especially under high-efficiency cutting conditions, where differences in tool performance become more apparent. As shown in Figure 4, after machining a single groove (cutting length of 130mm), the optimized arc-shaped end mill exhibited normal wear, while the corner radius end mill and ball-end milling cutter both experienced edge chipping, leading to tool failure. The optimized arc-shaped end mill only showed edge chipping and failure after a cutting distance of 10 meters, which is more than ten times the tool life of conventional corner radius end mills and ball-end mills.

Analysis of Experimental Results

The experimental results indicate that cutting hardened steel leads to significant tool wear. Under high-efficiency cutting conditions, tools face extreme situations where only those that meet the machining demands can be used; otherwise, they are unsuitable. The optimized arc-shaped end milling cutter, with its modified blade shape, redistributes the cutting forces, reduces the cutting load per unit length on the effective cutting edge, and improves the tool’s cutting performance, thereby meeting the demands of high-efficiency cutting.

How to Select End Milling Cutter Shapes for Machining Hardened Steel Mold Cavities? 60

Conclusion

This study focused on modifying the tool blade shape to meet the high-efficiency cutting requirements for hardened steel. Through general cutting simulations and cutting experiments, the following conclusions were drawn:

1.Cutting simulations and cutting force experiments revealed that the optimized arc-shaped end mill generates greater cutting forces, particularly in the axial direction, compared to conventional corner radius and ball-end mills. However, it has a lower cutting force per unit length, with cutting temperatures comparable to those of the corner radius end mill.

2.Cutting experiments demonstrated that due to the modified blade shape, the cutting load per unit length of the cutting edge is reduced. As a result, the optimized arc-shaped end milling cutter outperforms conventional corner radius and ball-end mills under high-efficiency and heavy-load cutting conditions in mold manufacturing.

 

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How Do Sintering Atmosphere and Particle Size Affect the Extrusion Forming Quality of Cemented Carbide Bars? http://www.owweac.cn/fr/cemented-carbide-quality/ http://www.owweac.cn/fr/cemented-carbide-quality/#comments Fri, 16 Aug 2024 07:45:13 +0000 http://www.owweac.cn/?p=22764 Cemented carbide is a significant type of cemented carbide, widely used in manufacturing cutting tools, wear-resistant parts, high-temperature alloy components, and other important applications. Factors such as extrusion forming processes, forming agents, sintering atmosphere, and magnetic properties all impact the performance and quality of WC+Co alloy. Studying the effects and mechanisms of these factors is crucial for optimizing the manufacturing process and enhancing the performance of cemented carbide. This article will explore the influence of sintering atmosphere and particle size on the quality of the extrusion forming process, providing theoretical and practical guidance for further understanding the manufacturing process and performance optimization of cemented carbide.

cemented carbide

Experimental Materials and Methods

Tungsten carbide (WC) powders were used as the raw material. Four different particle sizes of WC powder were selected: 4.0 μm, 2.2 μm, 1.1 μm, and 0.5 μm, which were labeled as WC1, WC2, WC3, and WC4, respectively. Metal cobalt (Co) powder was used as the binder phase, and paraffin was used as the forming agent. Four different WC-Co mixtures with varying particle sizes were prepared.

The mixtures were processed into green bodies with specific shapes and densities using extrusion forming equipment. The pressed green bodies were then placed in a sintering furnace and subjected to high-temperature sintering at 1400°C for 30 minutes, followed by cooling, to form cemented carbide bars.

The magnetic properties of the cemented carbide bars were tested using a magnetic performance tester, measuring parameters such as coercive force (Hc) and saturation magnetization (Bs), and the results were analyzed.

 

Experimental Results and Analysis

Table 1 presents the effects of different WC particle sizes on the coercive force (Hc) and saturation magnetization (Bs) of cemented carbide bars.
Table 1 presents the effects of different WC particle sizes on the coercive force (Hc) and saturation magnetization (Bs) of cemented carbide bars.

Effect of Particle Size on Coercive Force

As shown in Table 1, the coercive force of cemented carbide bars increases with decreasing WC particle size, while the saturation magnetization also increases. This indicates that cemented carbide bars made with fine and ultrafine WC particles exhibit poorer magnetic properties. Among the samples, the ultrafine WC (WC4) shows the highest coercive force of 4450 A/m, followed by medium-sized WC (WC3) with a coercive force of 3300 A/m. Coarse WC (WC2) and very coarse WC (WC1) have lower coercive forces, at 2350 A/m and 1200 A/m, respectively. The increase in coercive force with decreasing WC particle size is primarily due to the increase in internal defects and dislocations within smaller particles. These defects and dislocations create resistance to domain wall movement, making the magnetization process more difficult and requiring a larger external magnetic field to achieve saturation, thereby increasing the coercive force.

 

Effect of Particle Size on Material Magnetic Performance Stability

For fine and ultrafine WC particles, the larger grain boundary area facilitates grain boundary diffusion and reactions, which reduces the material’s magnetic properties. As the WC particle size decreases, the magnetic saturation of cemented carbide bars gradually increases. Specifically: coarse WC (WC1) exhibits the lowest magnetic saturation at only 1.25 T; medium-sized WC (WC2) has a magnetic saturation of 1.15 T; fine WC (WC3) and ultrafine WC (WC4) show higher magnetic saturations at 1.05 T and 0.93 T, respectively. This is likely because fine and ultrafine WC particles have higher chemical reactivity, promoting the diffusion and bonding of the Co binder, thereby improving the stability of the material’s magnetic performance.

Magnetic saturation is an indicator of the remaining proportion of magnetizable material and is closely related to magnetic properties such as coercive force and remanence. The impact of WC particle size on magnetic saturation can be attributed to the degree of solubility of the binder phase in the cemented carbide bars. Coarse and medium-sized WC particles, having larger specific surface areas, have more contact with the Co binder, which enhances the solubility of Co in the cemented carbide bars. This effectively improves the material’s magnetic performance stability, resulting in higher coercive force and better magnetic stability. Conversely, fine and ultrafine WC particles, with smaller specific surface areas, reduce the effectiveness of the Co binder, potentially affecting the material’s hardness and magnetic properties. Thus, selecting the appropriate particle size during the preparation of cemented carbide bars is crucial for achieving the best overall performance based on specific application needs.

 

Impact of Gamma Phase on Material Performance

For cemented carbide materials, the proportion of the gamma phase directly affects the material’s hardness and magnetic properties. Variations in carbon and oxygen content also influence the gamma phase proportion and must be considered during material preparation. Generally, higher carbon content leads to an increase in the gamma phase proportion, thereby enhancing the material’s hardness and magnetic performance. Therefore, different WC particle sizes may have varying carbon and oxygen contents, which also affects the gamma phase proportion and the overall performance of the material.

 

Discussion on Sintering Atmosphere

In the sintering process of cemented carbides, the choice and control of the atmosphere have a decisive impact on the final microstructure and magnetic properties of the material. The atmosphere not only affects the chemical reactions during sintering but also directly relates to the microstructure and final performance of the cemented carbide. The types of sintering atmospheres are as follows:

Oxidizing Atmosphere:? air.

Reducing Atmosphere: Contains components such as H? or CO: hydrogen atmosphere for cemented carbide sintering.

Inert or Neutral Atmosphere: Argon, helium, vacuum.

Carburizing Atmosphere: Contains high components that cause carburization of the sintered body, such as CO, methane, and hydrocarbon gases.

Nitrogen-Based Atmosphere: High nitrogen content sintering atmosphere: 10% H? in N?.

We mainly selected vacuum, argon, and hydrogen atmospheres for discussion. The variations in coercive force and magnetic saturation of cemented carbides sintered in argon, vacuum, and hydrogen atmospheres differ depending on the atmosphere, as shown in Table 2.

Table 2: Effects of Different Sintering Atmospheres on Magnetic Properties of Cemented Carbide Bars
Table 2: Effects of Different Sintering Atmospheres on Magnetic Properties of Cemented Carbide Bars

From Table 2, it can be observed that under vacuum and argon atmospheres, the coercive force (Hc) of cemented carbide bar is higher compared to that in a hydrogen atmosphere. Conversely, the saturation magnetization (Bs) is lowest in a hydrogen atmosphere compared to vacuum and argon atmospheres.

Under vacuum and argon atmospheres, the effective control of oxygen partial pressure and the exclusion of volatile elements result in fewer pores and inclusions, clearer grain boundaries, and better grain growth, thereby enhancing the magnetic properties of the material. In contrast, in a hydrogen atmosphere, the reducing nature of hydrogen may reduce some elements in the cemented carbide, leading to the presence of uncertain phase components, poor grain growth, and subsequently affecting the material’s magnetic properties.

For coercive force (Hc), it is largely dependent on the material’s microstructure and magnetic anisotropy. Under vacuum and argon atmospheres, effective control of oxygen partial pressure and exclusion of volatile elements reduce magnetic anisotropy in the cemented carbide, which improves coercive force. However, in a hydrogen atmosphere, hydrogen’s reducing effect can lead to the reduction of some elements in the cemented carbide, resulting in grain defects and inclusions that directly affect magnetic anisotropy and reduce coercive force.

Regarding saturation magnetization (Bs), the relative magnetic saturation value in cemented carbide is influenced by factors affecting carbon content in the alloy. In vacuum or argon atmospheres, effective control of oxygen content reduces carbon loss. Although the pressed green body contains oxygen, which can be reduced by free carbon and carbon in WC (MeO + C = Me + CO), the oxygen content in these atmospheres is relatively low. In a hydrogen atmosphere, decarburization reactions (WC + 2H? → CH? + C) begin at around 100°C. Throughout the preparation process, the material is exposed to a decarburizing atmosphere, leading to a lower relative magnetic saturation value.

How Do Sintering Atmosphere and Particle Size Affect the Extrusion Forming Quality of Cemented Carbide Bars? 62

Conclusion

This experiment investigated the effects of different particle sizes and sintering atmospheres on the magnetic properties of cemented carbide bars. By comparing the magnetic properties of cemented carbide under different WC particle sizes (coarse, medium, fine, and ultrafine) and sintering atmospheres (vacuum, argon, and hydrogen), it was found that both particle size and atmosphere have a significant impact on the magnetic performance of the material.

From the perspective of particle size, as the WC particle size decreases, the coercive force of the cemented carbide bars increases, while magnetic saturation also increases. This indicates that particle size has a substantial effect on the magnetic properties of cemented carbide. Fine and ultrafine WC particles, due to their higher chemical reactivity and good sintering performance, can promote the diffusion and bonding of the Co binder, thus enhancing the stability of the material’s magnetic performance. However, smaller particle sizes may lead to increased porosity and inclusions, affecting the material’s hardness and magnetic performance. Therefore, the choice of particle size should be tailored to the specific application needs when preparing cemented carbide.

Regarding the atmosphere, cemented carbide bars sintered under vacuum and argon atmospheres exhibited higher coercive force and better magnetic stability. This is because these atmospheres effectively control the oxygen content and volatile elements, reducing porosity and inclusions, and promoting clearer grain boundaries and grain growth. In contrast, cemented carbide bars sintered in a hydrogen atmosphere showed significantly lower magnetic saturation. This is likely due to the decarburizing effect of hydrogen. Therefore, selecting the appropriate sintering atmosphere is crucial for obtaining cemented carbide bars with excellent magnetic properties. Further improvements in cemented carbide performance can be achieved by optimizing sintering process parameters and adding suppressants.

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Caractéristiques techniques du fraisage à grande vitesse et ses applications dans l'industrie de fabrication de moules http://www.owweac.cn/fr/high-speed-milling/ http://www.owweac.cn/fr/high-speed-milling/#respond Sat, 10 Aug 2024 02:31:37 +0000 http://www.owweac.cn/?p=22755 High-speed milling technology has had a significant impact on mould processing procedures, transforming traditional processes such as “annealing → milling → heat treatment → grinding” or “electrical discharge milling → manual grinding and polishing” into streamlined processes where high-speed cutting can replace all previous steps. High-speed milling technology is not only suitable for the direct milling of hardened mould cavities (particularly for semi-finishing and finishing) but has also found widespread application in EDM electrode processing, rapid prototyping, and other areas. Extensive production practices have shown that using high-speed cutting technology can save about 80% of manual grinding time in subsequent mould processing, reduce processing costs by nearly 30%, achieve surface processing precision of 1 micrometer, and double the tool cutting efficiency.

Technical Characteristics of High-Speed Milling and Its Applications in the Mould Manufacturing Industry 65

High-Speed Cutting Milling Equipment

1.High Stability of Machine Bed Components

The bed and support components of a high-speed cutting machine must exhibit excellent dynamic and static stiffness, thermal rigidity, and optimal damping characteristics. Most machines use high-quality, high-rigidity gray cast iron for these components, with some manufacturers incorporating high-damping polymer concrete into the base to enhance vibration resistance and thermal stability. This not only ensures stable machine accuracy but also prevents tool chatter during cutting. Measures such as closed bed designs, integral casting of the machine bed, symmetric bed structures, and dense ribbing are also crucial for enhancing machine stability.

 

2.Machine Spindle

The spindle performance of high-speed machines is crucial for achieving high-speed cutting. High-speed cutting spindles typically operate at speeds ranging from 10,000 to 100,000 RPM, with spindle power greater than 15 kW. Spindle axial gaps between the tool holder and spindle are controlled to be no more than 0.005 mm using compressed air or cooling systems. Spindles are required to have rapid acceleration and deceleration capabilities, meaning they must have high angular acceleration and deceleration rates.

High-speed spindles often use liquid static pressure bearings, air static pressure bearings, hot-pressed silicon nitride (Si3N4) ceramic bearings, or magnetic suspension bearings. Lubrication is commonly achieved with oil-air lubrication or spray lubrication, and spindle cooling typically involves internal water or air cooling.

 

3.Machine Drive System

To meet the demands of high-speed mould processing, the drive system of a high-speed milling machine should have the following characteristics:

High Feed Speed: Research indicates that increasing spindle speed and feed per tooth is beneficial for reducing tool wear, especially for small-diameter tools. Common feed speed ranges are 20-30 m/min, with large lead ball screws allowing speeds up to 60 m/min and linear motors achieving up to 120 m/min.

High Acceleration: High-speed milling of complex 3D surfaces requires a drive system with good acceleration characteristics, with drivers providing high-speed feed (fast feed rate of about 40 m/min and 3D profile processing speed of 10 m/min) and accelerations and decelerations ranging from 0.4 m/s2 to 10 m/s2.

Most machine manufacturers use closed-loop position servo control with small lead, large-size, high-quality ball screws or large lead multi-head screws. Advances in motor technology have led to the development and successful application of linear motors in CNC machines. Linear motor drives eliminate issues such as mass inertia, overshooting, lag, and vibrations, speeding up servo response, improving servo control accuracy, and enhancing machine processing precision.

 

4.CNC System

Advanced CNC systems are key to ensuring the quality and efficiency of high-speed processing of complex mould surfaces. Basic requirements for CNC systems in high-speed cutting include:

High-Speed Digital Control Loop: Includes 32-bit or 64-bit parallel processors and hard drives with over 1.5 GB; extremely short linear motor sampling times.

Speed and Acceleration Feedforward Control: Digital drive systems with jerk control.

Advanced Interpolation Methods: Such as NURBS-based spline interpolation for good surface quality, precise dimensions, and high geometric accuracy.

Look-Ahead Function: Requires a large capacity buffer register to pre-read and check multiple program segments (e.g., up to 500 segments for DMG machines, and 1000-2000 segments for Siemens systems) to adjust feed speeds and avoid over-cutting when surface shapes (curvatures) change.

Error Compensation Functions: Includes compensation for thermal errors due to linear motors and spindles, quadrant errors, measurement system errors, etc. Additionally, high data transmission speeds are required.

Data Interfaces: Traditional data interfaces like RS232 serial ports transmit at 19.2 kb, while many advanced milling centers now use Ethernet for data transmission at speeds up to 200 kb.

Technical Characteristics of High-Speed Milling and Its Applications in the Mould Manufacturing Industry 66

5.Cooling and Lubrication

High-speed milling uses coated carbide tools and operates without cutting fluids, resulting in higher cutting efficiency. This is because the high centrifugal forces of the rotating spindle make it difficult for cutting fluids to reach the cutting zone, and even if they do, the high temperatures may cause the fluids to evaporate, reducing cooling effectiveness. Additionally, cutting fluids can cause rapid temperature changes at the tool edge, leading to cracking. Thus, dry cutting with oil/air cooling is employed. This method quickly blows away the cutting heat with high-pressure air, and atomized lubrication oil forms a thin protective film on the tool edge and workpiece surface, effectively extending tool life and improving surface quality.

milling cutters

Tools for High-Speed Cutting

Tools are one of the most critical factors in high-speed cutting, directly impacting processing efficiency, manufacturing costs, and product precision. High-speed cutting tools must withstand high temperatures, pressures, friction, impact, and vibrations. They should have good mechanical properties and thermal stability, including impact resistance, wear resistance, and thermal fatigue resistance. The development of high-speed cutting tools has been rapid, with common materials including diamond (PCD), cubic boron nitride (CBN), ceramic tools, coated carbide, and titanium carbide (TiC) and titanium nitride (TiN) hardmetals.

For cutting cast iron and alloy steel, carbide is the most commonly used tool material due to its good wear resistance, although its hardness is lower than CBN and ceramics.

To improve hardness and surface finish, coating technologies such as titanium nitride (TiN) and aluminum titanium nitride (TiAlN) are employed. Coating technology has evolved from single-layer to multi-layer and multi-material coatings, becoming a key technology for enhancing high-speed cutting capabilities. Carbide inserts with titanium carbonitride coatings in the diameter range of 10-40 mm can process materials with Rockwell hardness below 42, while titanium aluminum nitride-coated tools can handle materials with Rockwell hardness of 42 or higher.

For high-speed cutting of steel, tools made from heat-resistant and fatigue-resistant P-class carbide, coated carbide, CBN, and CBN composite materials (WBN) are preferred. For cutting cast iron, fine-grain K-class carbide should be used for roughing, and composite silicon nitride ceramics or polycrystalline CBN (PCBN) tools for finishing.

For precision milling of non-ferrous metals or non-metallic materials, polycrystalline diamond (PCD) or CVD diamond-coated tools are recommended. When selecting cutting parameters, attention should be given to the effective diameter for round blades and ball end mills. High-speed milling tools should be designed with dynamic balancing, and the cutting edge angles should be adjusted compared to conventional tools.

High-Speed Milling Processes and Strategies

High-speed machining includes roughing, semi-finishing, finishing, and mirror finishing to remove excess material and achieve high-quality surface finishes and fine structures.

 

Rudesse

The primary goal of mould roughing is to maximize material removal rate per unit time and prepare the geometric profile of the workpiece for semi-finishing. The process plan for high-speed roughing involves a combination of high cutting speeds, high feed rates, and small cutting depths. The most commonly used CAM software employs methods like spiral contouring and Z-axis contouring, which generate continuous, smooth tool paths in a single pass without retracting the tool, using arc entry and exit methods. Spiral contouring avoids frequent tool retraction and approach, minimizing the impact on surface quality and machine wear. Steep and flat areas are processed separately, with optimized tool paths generated using spiral methods with minimal retraction to achieve better surface quality. In high-speed milling, it is essential to use arc entry and exit methods and maintain a consistent tool path to minimize machine wear and achieve higher material removal rates.

 

Semi-Finishing

The semi-finishing process focuses on improving surface quality and dimensional accuracy, bridging the gap between roughing and finishing. The cutting speeds are higher than those used in traditional milling but lower than those in finishing. The primary goal is to achieve a better surface finish and precision by using a reduced depth of cut and controlling feed rates. Advanced CAM systems generate tool paths using techniques like trochoidal milling and adaptive clearing, which adaptively change cutting parameters based on the workpiece geometry and tool path. This method enhances tool life and surface quality while reducing cutting forces and thermal stresses.

 

Finition

Finishing operations aim to achieve the final surface quality and dimensional accuracy. High-speed finishing involves higher cutting speeds and lower depths of cut, using techniques such as high-speed finishing cuts with constant engagement to ensure a smooth and uniform surface. Tool paths are optimized using advanced CAM software to achieve the desired surface finish and accuracy. Techniques like high-speed trochoidal milling and constant chip load milling are used to achieve excellent surface finishes and tight tolerances.

 

Mirror Finishing

Mirror finishing is the final step to achieve an exceptionally smooth and reflective surface. High-speed mirror finishing processes often involve special tools and techniques, including abrasive tools and polishing compounds. The key is to minimize surface irregularities and achieve a mirror-like finish with high precision. Techniques such as high-speed burnishing, polishing, and super-finishing are employed to achieve the desired surface quality.

 

Conclusion

High-speed milling technology has revolutionized the mould manufacturing industry by significantly enhancing machining efficiency, precision, and surface quality. The integration of advanced machining equipment, CNC systems, tooling technologies, and innovative milling strategies has enabled the production of complex mould cavities with high accuracy and reduced processing times. As technology continues to advance, high-speed milling will play an increasingly crucial role in meeting the evolving demands of the mould manufacturing industry.

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