1. ????? ????? ???????? ???????

Cryogenic treatment usually adopts liquid nitrogen cooling, which can cool the workpiece to below – 190 ℃. The microstructure of the treated material changes at low temperature, and some properties are improved. Cryogenic treatment was first proposed by the former Soviet Union in 1939. It was not until the 1960s that the United States applied the cryogenic treatment technology to the industry and began to use it mainly in the aviation field. In the 1970s, it expanded to the machinery manufacturing field.

????? ???? ??????? ???????? ? ???? ??????? ??? ????? ????? ?????? ???. ???? ??????? ??????? ?? ?????? ?? ???? ????? ?????? ?????? ?? ?????????? ?????? ?????? ???? ????? ??? ???? ????? ?????????? ?????? ? ???? ???????? ????? ????? ??? ???? ??????? ??? ????? ????? ????? ? ?? ??? ??????? ???????? ??? ???? ????? ????? . ?? ????? ?????? ?? ???? ?????? ??????? ???? ??????? ???? ??????? ? ??? ?? ????? ????? ???? ??? ???? ????? ??????? ?????? ??? ?? ??????? ?? ????? ?? ??? ???? ?????. ????? ??????? ??????? ????? ?????? ? ??? ???? ?????????? ??????.

2- ????? ???????? ??????? ??????

The gas principle is to cool by the gasification latent heat of liquid nitrogen (about 199.54kJ/kg) and the heat absorption of low-temperature nitrogen. The gas method can make the cryogenic temperature reach – 190 ℃, so that the cryogenic nitrogen can contact the materials. Through convection heat exchange, the nitrogen can be vaporized in the cryogenic box after being ejected from the nozzle. The workpiece can be cooled by the latent heat of gasification and the heat absorption of cryogenic nitrogen. By controlling the input of liquid nitrogen to control the cooling rate, the cryogenic treatment temperature can be automatically adjusted and accurately controlled, and the thermal shock effect is small, so is the possibility of cracking.

?? ????? ?????? ? ????? ????? ????? ??? ??? ???? ???? ?? ??? ???????? ?? ??????? ? ?????? ??????? ?????? ??? ????? ?? ????? ???? ???? ??????? ????? ????? ???? ?????? ????. ???? ???????? ??????? ?? ???? ???? ???? ?? ??? ?????? ??????? ?????? ????? ????? ??????? ???????? ???????? ??? ???????? ???????? ???????? ?????? ?? ?????? ? ?? ????? ???????? ????? ????? ?????.

?? ??????? ?? ??????????? ??????? ??????? ???????? ???? ??? ?? ??????????? ???????????. ????? ????????? ?? ??????? ?? ??? 1981 ? ???? ?????? ??????? ?? ???????? ??????? ?? ??? 1992 ?? ???? ????????? ????????? ?? ???? ???? ????? ??? ???????? ???????. ??? ???????? ????? ?????? ? ??? ????? ?????? ??? ???????? ??????? ?? ?????? ??????. ??? ??? ??????? ???????? ?????? ????????? ??????? ???????? ???? ???? ?? ??????? ???????? ??????? ?????? ??? ???? ??????? ???????? ? ??????? ?????? ???? ????? ???????? ???????.

3. ????? ???? ???????? ????????

????? ????? ???????.

Co ?? ????? ??????? ?? ???? ????? ???? ????????? ????????? (fcc) ????? ?????? ?????? ????? ????? ε ??????? (hcp). ε- ???? Co ??? ????? ?????? ???? ??????? ???? ????. ???? ?? 417 α ?????? ????? ????? ?????? ? ???? ???? ??? ??? Co α. ??? ?? 417 ℃ ???? ??? ?????? ?? ????? ? ??? ????? ??? ???? ????? ????? α ?????? ??? ??? ???? ??? ?????? ε ???. ??? ??? ? ????? ??????? WC ? α ? ??? ???? ???? ??? ??????? ?? ??????? ????? ?? ????? ?? ???? ???? ??? ?????? ????? ? ??? ???? α → ε ????? ????? ?????? ???? ????? ?????? ???? ??????? ??? ??? ?? 417 ℃ α ?? ???? ????? ????? ?????? ?? ε ???????. ???? ????? ???????? ??????? ???? ???? α ? ε ??? ?????? ?????? ?? ??????? ? ???????? ????? ????? ??????? ?????? ????? ε ????? ????? ?????. ??????? ??????? ???????? ??? ???????? ??????? ? ??? ??? ?????? ??????? ?? Co ????? ??? ??? ???? ???? ?????? ?????? ??????? ? ??? ?? ???? ?? ??????? ?????? ?? ?????? Co ? ????? ???? ????? ? ????? ????? ?? ????? ??????? ??????? ??????.

????? ??????? ??????? ??????.

???? ??????? ??? ???????? ??????? ?? ??????? ????????? ??????? ?????? ?????. ????? ?????? ?? ???????? ?? ???? ????? ????? ????????? ??????? ?? ?????? ??????? ???? ?? ???? ???? ???? ?? ??? ??????. ????? ????? ????? ????? ??????? ??? ??????? ? ???? ????? ??????? Co ???? ???? ? ????? ?????? WC ???? ?????. ?? ????? ???? ?? ??? ???? ??? ?????? ? ???? ????? ??? ???????? ?? ????? ????? ????? ?????? ?????? ?? ??????? ?????? ???? ?? ???? ?????? ????? ???? ?????? ?? ????? ??????? ????? ????? ??????? ??? ??????? ? ?? ??? ?????? ??? ????? ????????? ? ??? ???? ?? ????? ?????? ???????.

????? ??????? ??????

?????? ?? η ?????? ????? ?? ?????? WC ???? ???????? ???? ?????? ??????? ? ????? η ????? ????? ?????? Co ?? ????????. ???? ?????? ????? Co ?? ????? ??????? ??? ????? ???????? ???????? ?????? ?????? ? ??? ?? ????? ??? ???? ??????? ?????? ???? ????? ?? ??????? ??????? ????????. ????? ?????? ???????? ???????? ? ???? ????? ??????? ?????? ?????? ?????? ???? ? ?? ????? ?????? ?????? ?????? ????? ??????? ??????? ??????? ????????. ????? ????? ????? ??? ??? ???????? ??????? ? ???? ?????? ?????? Co ? ??? ????? ????? ?????? ?? Co ?? ???????? ??????? WC. ????? ??????????? ?? ??????? ?????? ?? ??? ???? ?????? ??????? ???????.

4 ???? ?? ???? ??????? ?????? YG20 ?? ???????? ???????

????? ????? ???????? ??????? ?????? ?????? ?????? YG20:

(1) ??? ?????? ?????? ?????? ?? ??? ???????? ??????? ?

(2) Start the cryogenic tempering integrated furnace, open the liquid nitrogen, reduce it to – 60 ℃ at a certain rate, and keep the temperature for 1h;

(3) Reduce to – 120 ℃ at a certain rate, and keep the temperature for 2h;

(4) Reduce the temperature to – 190 ℃ at a certain cooling rate, and keep the temperature for 4-8h;

(5) ??? ?????? ??? ??????? ? ??? ??? ???? ??????? ??? 180 ???? ????? ????? ?? 0.5 ???? / ????? ???? 4 ?????

(6) ??? ?????? ????? ???????? ? ???? ????? ??????? ???????? ???????? ???? ????? ??? ???? ????? ??????.

???????: ???? ??????? ?????? YG20 ???? ?????? ????? ???? ???????? ??????? ???? ???? Φ 3.8 ???? ????? ?? ????? ???????? ? ???? ??????? ?? ??? ???? ?????? ??? ???????? ??????? ???? ????? ?? 15% ?? ??? ?????? ???? ???????? ??????? .

???? ?????? ??? ????????? ?? ??? ??? ???????? ??????? ? ??? ????? ???????? ?????? ???????? ?? ????? (fcc) ?? YG20 ??? ???????? ??????? ???? ???? ? ε- ??????? ??????? ?? Co (hcp) ?? ????? ??? ????? ?????? ?????? ? ??????? ??????? ????????? ?????????.

5. ???? ????? ???????? ???????

????? ????? ??????? ?????? ????? ??????? ???????? ?? ???????? ??????? ?? ??? ???? ??????? ????? ??????? ??? ???????? ????? ?????? 2 ??? 8 ???? ? ????? ???? ???? ??????? ???? ????? ????? ??????? ??? ?????? ?? ??? ?????? ???? ????. ?? ?????????? ? ?? ????? ??? ???? ??? ??????????? ??????? ??????? ???????? ? ??? ????? ????? ??? ?????.

???? ??? ? ????? ?? ????????? ???????? ??????? ??????? ???????? ??? ?????? ???? ????? ?? ????? ?????? ? ??? ?? ??????????? ???? ?? ?????? ????? ??? ????? ? ????? ???? ????? ??? ???? ?? ????????? ??????? ?? ??? ????????. ????? ??????? ????? ??????? ? ???? ???????? ??????? ???? ????? ??? ????? ?????? ?????? ???? ???? ????? ??????? ? ???? ??? ??? ????? ???? ??? ??????? ??????????.

Edge radius processing is an indispensable process after fine grinding of CNC tools and before coating. The purpose is to make the cutting edge smooth and smooth, and extend the tool life. There are 9 methods of edge radius treatment of CNC tools introduced by Meetyou. Let’s get to know it.

???? ?????? ??? ??? ?????? ?????? ????? ?? ???? ???????? ??? ????? ????? ?????? ?????? ???? ????? ?????? ??? ?? ??? ????? ?????? ?????? ??????? ?????? ??????? ?????? ??????.

1. ?????? ?????? ?????? ??????

?? ????? ?????? ???? ??????? ??? ?????? ???????? ?????? ???? ?????? ????? ???? ????? ???? ?????? ?????????? ??? ???? ??????? ??????? ?????? ??????. ???? ?? ????? ?????? ??????? ??????? ?? ????? ????? ??????? ????? ??????? ?????? ????? ????? ???????.

2. ?????? ??? ????? ???? ?????

??? ????? ?????? ???? ????? ?????? ?? ???? ??????? ?????? ??? ???? ????? ?????????? ?????. ??? ?????? ???????? ????? ???? ????? ?????? ???? ??????? ????? ????? ????? ?????? ?????? ????? ????? ??? ???? ????? ????? ??? ???? ?????.

3. ????? ????? ??????? ?????

???? ?? ???? ????? ????? ?????? ??? ????? ???? ????? ????? ????? ???????. ???? ??? ??? ??????? ???? ?????? ???? ???? ????? ??????? ????? ????? ????? ??? ???? ???????.

??? ??????? ????????? ????? ????? ??? CNC ?????? ?? ?????? ??????? ??? ?????. ??? ?????? ???? ?? ???? ?????? ?? ???? ????? ????? ????????? ??? ???? ???? ???? ?? ??????? ???????? ????? ????? ????? ???? ???? ?? ???? ?????.

9 ????? ?? ??? ?????? ??? ??? ??????

????? ??? ??? ???? ???? ?????

??? ?? ????? ??????? ?????? ??????? ?????????.

????? ??? ??? ???? ????? ????????

???? ????? ????? ????? ????? ??????? ?? ???????? ??????? ??? ???? ??????? ?? ??? ??????? ?? ???? ????????? ?????? ????? ?????? ?? ???? ??????? ???? ?????? ???????.

????? ??????? ??????

??? ????? ??? ????? ????? ????? ?????? ????? ?????. ???? ????? ????? ????? ??????? ??? ??? ??????. ????????? ?? ????? ????? ????????? ??? ??? ??????? ???? ??????? ???? ??????.

????? ??????? ??????? ??? ??? ??????

????? ??? ??????? ?? ??? ?????? ??????? ?? ??? ?????? ??????? ??? ????????? ???? ??? ?????? ?? ???? ?????? ?????? ????? ???? ????????. ?? ????? ?????? ?? ??? ??????? ???? ????? ?? ????? ????? ????????.

?????? ??? ??? ?????? ??????????? ??????????????

??? ????? ????? ???? ??? ???????? ?????????????? ?????? ??????????. ?????? ????? ?????? ???????? ?????????? ??? ?? ????? ?????????? ?????? ???? ???????.

????? ??????: ?? ????? ????? ?? ??????? ??? ???? ????? ?????? ???????. ?????? ????? ????? ????? ??? ??? ?????? ???????? ?????? ??? ??????? ?????? ????? ????? ??????.

????? ?????? ??? ??? ???? ????????

 ????? ???? ???????? ??????? ??? ????? ?????? ?????? ???. ??? ??? ?????? ?? ????? ????? ???? ????????. ??????? ????? ????????? ???????. ????? ???????? ??????? ??????? ???? ????? ?????? ?????? ?????? ???????? ??? ???? ????? ?? ???? ???????? ?????? ????? ??????.

????? ????? ??????????

This is a edge radius processing that applies a magnetic field in the direction perpendicular to the axis of the cylindrical surface of the workpiece, and adds magnetic abrasive between the magnetic field S and N poles. The magnetic abrasive will be adsorbed on the magnetic pole and the workpiece surface, and will be arranged into a flexible “abrasive brush” along the direction of the magnetic line of force. The cutter rotates and vibrates axially at the same time to remove the metal and burrs on the workpiece surface.

????? ??? ????? ??????? ???????: ????? ?????? ????? ?????? ??????? ????? ???? ????? ????? ???? ????? ?????? ?? ???? ?????? ?? ????? ???? ??????? ????? ?????? ??????? ?? ???? ???????? ???? ?????? ???????? ??? ???? ?????.

Etching is a technology that uses chemical strong acid corrosion, mechanical polishing or electrochemical electrolysis to treat the surface of objects. In addition to enhancing aesthetics, it also increases the added value of objects. From traditional metal processing to high-tech semiconductor manufacturing, they are all within the scope of application of etching technology.

Metal etching is a technology to remove metal materials through chemical reaction or physical impact. Metal etching technology can be divided into wet etching and dry etching. Metal etching consists of a series of chemical processes. Different etchants have different corrosion characteristics and strength for different metal materials.

Metal etching, also known as photochemical etching, refers to the removal of the protective film of the metal etching area after exposure, plate making, development and contact with the chemical solution in the process of metal etching, so as to achieve dissolution corrosion, formation of bumps, or hollowing out. It was first used to manufacture printed concave convex plates such as copper plate and zinc plate. It is widely used to reduce the weight of instrument panel or process thin workpieces such as nameplate. Through the continuous improvement of technology and process equipment, etching technology has been applied to aviation, machinery, chemical industry and semiconductor manufacturing processes for the processing of precision metal etching products of electronic thin parts.

Types of etching technology

Wet etching:

Wet etching is to immerse the wafer into a suitable chemical solution or spray the chemical solution onto the wafer for quenching, and remove the atoms on the surface of the film through the chemical reaction between the solution and the etched object, so as to achieve the purpose of etching During wet etching, the reactants in the solution first diffuse through the stagnant boundary layer, and then reach the wafer surface to produce various products through chemical reactions. The products of etching chemical reaction are liquid or gas phase products, which are then diffused through the boundary layer and dissolved in the main solution. Wet etching will not only etch in the vertical direction, but also have the effect of horizontal etching.

Dry etching:

Dry etching is usually one of plasma etching or chemical etching. Due to different etching effects, the physical atoms of ions in the plasma, the chemical reaction of active free radicals and the surface atoms of devices (wafers), or the combination of the two, include the following contents:

physical etching: sputtering etching, ion beam etching

chemical etching: plasma etching

physicochemical composite etching: reactive ion etching (RIE)

Dry etching is a kind of anisotropic etching, which has good directivity, but the selectivity is worse than wet etching. In plasma etching, plasma is a partially dissociated gas, and gas molecules are dissociated into electrons, ions and other substances with high chemical activity. The biggest advantage of dry etching is “anisotropic etching”. However, the selectivity of dry etching is lower than that of wet etching. This is because the etching mechanism of dry etching is physical interaction; Therefore, the impact of ions can remove not only the etching film, but also the photoresist mask.

Etching process

According to the type of metal, the etching process will be different, but the general etching process is as follows: metal etching plate → cleaning and degreasing → water washing → drying → film coating or silk screen printing ink → drying → exposure drawing → development → water washing and drying → etching → film stripping → drying → inspection → finished product packaging.

1. Cleaning process before metal etching:

The process before etching stainless steel or other metals is cleaning treatment, which is mainly used to remove dirt, dust, oil stains, etc. on the material surface. The cleaning process is the key to ensure that the subsequent film or screen printing ink has good adhesion to the metal surface. Therefore, the oil stain and oxide film on the metal etching surface must be completely removed. Degreasing shall be determined according to the oil stain of the workpiece. It is best to degrease the silk screen printing ink before electric degreasing to ensure the degreasing effect. In addition to the oxide film, the best etching solution shall be selected according to the type of metal and film thickness to ensure surface cleanliness. It must be dry before screen printing. If there is moisture.

2. Paste dry film or silk screen photosensitive adhesive layer:

According to the actual product material, thickness and the exact width of the figure, it is determined to use dry film or wet film silk screen printing. For products with different thicknesses, factors such as the etching processing time required for product graphics should be considered when applying the photosensitive layer. It can make a thicker or thinner photosensitive adhesive layer with good coverage performance and high definition of patterns produced by metal etching.

3. Drying:

After the completion of film or roll screen printing ink, the photosensitive adhesive layer needs to be thoroughly dried to prepare for the exposure process. At the same time, ensure that the surface is clean and free of adhesion, impurities, etc.

4. Exposure:

This process is an important process of metal etching, and the exposure energy will be considered according to the thickness and accuracy of the product material. This is also the embodiment of the technical ability of etching enterprises. The exposure process determines whether the etching can ensure better dimensional control accuracy and other requirements.

5. Development:

After the photosensitive adhesive layer on the surface of the metal etching plate is exposed, the pattern adhesive layer is cured after exposure. Then, the unwanted part of the pattern, that is, the part that needs corrosion, is exposed. The development process also determines whether the final size of the product can meet the requirements. This process will completely remove the unnecessary photosensitive adhesive layer on the product.

6. Etching or etching process:

After the product prefabrication process is completed, the chemical solution will be etched. This process determines whether the final product is qualified. This process involves etching solution concentration, temperature, pressure, speed and other parameters. The quality of the product needs to be determined by these parameters.

7. Removal:

The surface of the etched product is still covered with a layer of photosensitive adhesive, and the photosensitive adhesive layer on the surface of the etched product needs to be removed. Because the photosensitive adhesive layer is acidic, it is mostly expanded by acid-base neutralization method. After overflow cleaning and ultrasonic cleaning, remove the photosensitive adhesive layer on the surface to prevent photosensitive adhesive residue.

8. Test:

After the film is taken, the following is testing, packaging, and the final product is confirmed whether it meets its specifications.

Precautions in etching process

reduce side corrosion and protruding edges and improve metal etching processing coefficient: generally, the longer the printed board is in the metal etching solution, the more serious the side etching is. Undercutting seriously affects the accuracy of printed wire, and serious undercutting will not make thin wire. When the undercut and edge decrease, the etching coefficient increases. The high etching coefficient indicates that the thin line can be maintained and the etched line is close to the size of the original image. Whether the plating resist is tin lead alloy, tin, tin nickel alloy or nickel, the excessively protruding edge will lead to short circuit of the conductor. Because the protruding edge is easy to break, an electric bridge is formed between two points of the conductor.

improve the consistency of etching processing rate between plates: in continuous plate etching, the more consistent the metal etching processing rate, the more uniform etching plate can be obtained. In order to maintain the best etching state in the pre etching process, it is necessary to select an etching solution that is easy to regenerate and compensate and easy to control the etching rate. Select technologies and equipment that can provide constant operating conditions and automatically control various solution parameters. It can be realized by controlling the amount of copper dissolved, pH value, solution concentration, temperature, uniformity of solution flow, etc.

improve the uniformity of the metal etching processing speed of the whole plate surface: the etching uniformity of the upper and lower sides of the plate and each part of the plate surface is determined by the uniformity of the flow rate of the metal etching solution on the plate surface. In the etching process, the etching rates of the upper and lower plates are often inconsistent. The etching rate of the lower plate surface is higher than that of the upper plate surface. Due to the accumulation of solution on the surface of the upper plate, the etching reaction is weakened. The uneven etching of the upper and lower plates can be solved by adjusting the injection pressure of the upper and lower nozzles. The spray system and the oscillating nozzles can further improve the uniformity of the whole surface by making the spray pressure of the center and edge of the plate different.

Advantages of etching process

Because the metal etching process is etched by chemical solution.

maintain high consistency with raw materials. It does not change the properties, stress, hardness, tensile strength, yield strength and ductility of the material. The base processing process is etched in the equipment in an atomized state, and there is no obvious pressure on the surface.

no burrs. In the process of product processing, there is no pressing force in the whole process, and there will be no crimping, bumping and pressing points.

it can cooperate with the post process stamping to complete the personalized molding action of the product. The hanging point method can be used for full plate electroplating, bonding, electrophoresis, blackening, etc., which is more cost-effective.

it can also cope with miniaturization and diversification, short cycle and low cost.

Application field of etching processing

consumer electronics

filtration and separation technology

Aerospace

medical equipment

precision machinery

car

high end crafts

????? ??????? ?? ??? ?? ????? ??????? ????? ?? ????? ????? ???????? ?? ?????? ????? ??????? ???????? ????? ???????. ???? ????? ???? ???? ? ???? ?????? ??? ???? ???? ?? ?????? ?? ????????. ?? ?????? ???? ????? ??????? ??????? ??????? ?????? ????? ????? ??????? ???? ????? ???? ????? ? ??? ???? ???? ????? ??????? ??????? ???? ????? ??????? ????????. ?? ??????? ???????? ??????? ? ???? ?????? ?? ???????? ??????? ??????? ??? ???????? ??????? ??? WC ?????? ??? ????? ?? ????? ?????.

????? ?????

WC-Co

?????? ????????? ????????? ??? ???? ???? ?? ????? ???????? ?? ????????. ??? ????? ???? WC Co ??? ???? ????. ????? ???? ????? ??????? ???? WC ????? ???????? ????????? ???????. ???????? ??? ??? ? ??? ?? ???? ?? ????? 13.2 ? ???? ?? ???? ????? ???? ????? ??????? ????? ??? ????? ????? ???????? ???? ????.

????? 13.3 ????????? ???????? ????? ?????? WC Co ???? ??????? ???????? ??????????: (?) ? (?) F8 ? (?) ? (?) M8 ? ? (??) ? (?) ? 8.

???? ??????? ?????????? ??????? ??????? F8 ? M8 ? C8 ???????? ????????. ???? ?? ???? ????? ??????? ??? ??? ???? ??????. ????? ????? F8 ??????? ?????? ????????? ??????? ? ????? ????? ????? M8 ? C8 ???? ????? ?????? ?????? ?? ??? ??????. ?? ????? ??????? ? ???? ???? ??????? ????? ???? ????? ? ??????? ?????? ??????? ?????? ???? ???? ?? ????? ????????. ?????? ????? ????? (HV) ?? 1500 ??? 2000 HV30 ? ??????? ????? ????? ?? 7 ??? 15 ???? ?????? M1 / 2. ??? ??????? ?????? ?? ????? ????? ??????? ? ??????? ???????? ??????? ?????????.

???? ??? ? ???? ??? ??? ???????? ???? ? ???? ???? ??????? ????? ?????? ?????? ????. ???? ??? ??? ??? ???? ????? ??????? ? ???? ????? ????? ? ???? ???? ??? ????? ??????? ?????? (??? ?????? ? 2007). ???? ? ?? ??? ?????? ??? ???? ???? ? ?? ?? ?? ??????? ?? ??????? ???? ??????? ???? ????? ?? ???.

?? ????? ???? ? ????? ??????? ???????? ????? ? ??? ???? ????? ?? ???????????? ??? ????? ??????? ??? ????? ?????. ???????? ??? ??? ? ??? ?????? WC ??????? ??????? ???? ??? ????? ????? ???? ????? ?? ?? ??????? ????.

WC- ??

?????? ???? ????? ?? ?????? ???? ?? ????????. ????? ????? ????? ????. ???? ???????? ?????? ???? ?????? / ??????? ? ???? ????? ??????? ??????? ??????? ?????? ?? ?????? ???????. ????????? ?? ????? WC Co ? ??? ????? ?????? ???. ????? ??? ?????? ???? ????? ?? WC ? ???? ?????? ????? ????? ?????? WC ? ??? ???? ??? ???? ????? ???? ??????.

WC-Ag

????? Ag ???? WC ????? ?? ?????? ???????? ?????. ??? ????? ???? ????? ?????? ? ?????? ?? ??? ????? WC ?? ????? ??????? ? ????? ???? ?? ???? ??? ?????? ??????? ?????????? ???????? (RC) ???????. ??? ?????? ?????? ?? ?????? ?????? WC Ag ????? ?? ????? ????? Ag ? ???? ??????? ?? ????? ????? Ag ? ????? ???? ??? ???????? ?????? ??? ????? WC ? Ag. ???????? ??? ??? ? ????? ?????? WC ?????? ??????? ????? ?????? ???? ???????.

???? ????? 13.4 ????? ?????? ??????? ????????? (RC) ???? ?????? ???????

???? 11e50 ?????? ??? ????? ???? ?????? ????? ? ??? ???? ?? RC ????? ?????? ?????? ??? 10 ????? ?????. ?????? ?????? ??????? ????? ??? 50-55 wt% (???? ??? 60% ? 64.6%) ?? WC ?? ??? ????? 4 ?? ? ???? 55-60 wt% (???? ??? 64.6% ? 69%) ?? WC ???? ???? 0.8 ? 1.5 ???. ???? ? ???? ??? ??????? ?????? ????????? ? ??? ???? ?????? Ag ??????? ???? ????. ??????? ???????? ??????? ? ???? ?????? ?? ?????? ??????? ??? 1.5 ? 4 ?? ??? ???? WC ? ????? ???? ????? ??? ???? ??????.

WC- ?????

?????? ??????? ????? ???????? ?????? ???????? ?? ??? ?????? ??? ???? ???? ?? WC Co ? ??? RE ???? ?? ???? ????? ????? ?? ???? ??????? ????? ???

????? 13.4 ???? ????? ?????? ??????? ????????? ??? ????? Ag ????? ???? ???? WC ??? ?????? ??????? ?????? WC ???? ??????? 11 ??? 50 ?? co ?? Ni. ????? ?????? ?????? ???????? ??????? WC (????? 20% RE) ? ?? ??? ?? ?????? WC ?????? ?? ??? ????? ??????? ??????? ?? ????? ???? HCP ? ???????? ????? ????? ???????. ??? ??? ???????? ????? WC Ni ?????? ????????? ??????. ????? ????? ????? ??????? ????? ???? WC Co ? ??? ??????? ??????? ?????? ????? ???? ???????. ????? ?? ??? ???????? ??????? ?????? ?????? ?????? ?????? ??? ???? ??? ????? ?????? ? ???? ???? ?? 2400 ??? / ?? ~ 2 ?? HV (?????? ?? 1700 ??? / ?? ~ 2 ?? WC-Co)

??????? ??? ????? ??????

WC-FeAl

?? ?????? ??????? ??????? ? ?????? ???????? ???????? ??? ?????? ??????? ??????? ?????? ?????. ????? ???????? ????? ??? ?????? ?????? ??????? ??????? ?????? ? ????? ?????? ? ?????? ????? ? ??????? ???? ?????? ? ???????? ???? ????? ????? ? ??????? ?????. ??? ?????? ???????? ?????? ???????? ?????. ????? ???? ????? ?? WC FeAl ? WC Co ???????? ?? ??????. ?????? ????? ??????? ?????? ?????? WC Co ?? ??? ?????? ?????? WC Co ?????????. ???? ?????? ??? ??? ??? ?? ?????? ????? ??? ?????? ? ??? ?????? ??????? ???? ???????? ?????????. ???? ????? 13.5 ????? ????? ??? ???????? ??????? ??????? WC FeAl ?????? ?????? ?????? ??? ? / ?? ????? ??????. ????? ????????? ??????? ?? ????? 13.5 ??? ????? ????? ?????. ?? ????? 13.5 ? ?????? ?????? ?????? ???? ???????? ?????? ?? ?????? ?????? ????? WC ????. ?????? ???? ?????? ??????? ???? ???????? ?????? ?? ???? ?????? ?????? FeAl ???? ????? ??? ??? ?????? WC. ????? ????? ?????? ??????? ? ?? ????? ?????? ?????? ??? ????? ????? ? / ?? ???????. ????? ????? ??????? ?????? DR (????????? ?????? ????? ??????? ??????) ??? ?????? ???????? ???????? ????????.

????? 13.5 ??????? ??? ???????? ??????? WC-FeAl ???????? ??????? ?? ?????? ????? ??????.

WC- ???????

WC-MgO

?? ??????? ?????? ??????? Wc-mgo ??? ???? ???? ???? ????? ?????? MgO ?? ?????? WC ? ????? ??? ????? ???? ??? ??????? ????? ???? ???? ?? ????? ??????. ?????? ??????? ????? ?? ??????? ? ???? ?? ???? ??? ??????? ? ??? ?????? ??? ??????? ????? ???? ????? ??????? ?????? ????. ?? ????? ???? ????? ?? VC ? Cr3C2 ??????? ??? ?????? ?????? ??? ?????? ???????? ?? ?????? ??? ?????? ?? ??? ?????? ?? ????? ??????? ? ???? ????? ????? ?????? ??????????? ??????.

WC-Al2O3

??? ?? ???? ??? ?? Al2O3 ?????? ????? ????? ??????? ? ?????? ?????? ? ???? ?????? ??????????? ??????????? ????????.

???? ????? ?????? ???? ???????? ??? ??????? ????? ??? ?????? ???????? ???????? ??????????? ????? wc-40vol% Al2O3. ?? ????? ???? ????? ??????? ???? ???????? ? ????? ??????? ??????? ???? ????????. ?? ????? ???? ? ????? ??? ????? ?????? ?????? ????? ????? ?? ?????. ???? ?????? ???????? ????? ?????? ?? ???? ??? ?????? ??????? ??????. ?? ???????? wc-40vol% Al 2O 3 ? ??? ???? ??????? ???????? ?? ????? ?????? ?????? ???????. ???? ????? ???? ?? HV ????? 20e25gpa ?????? ????? ?? 5e6mpa.m1 / 2.

???? ????? 13.6 ????? ???????? ?? ??????? ?????? ????? ???? ????? ?????? ?? ????? ?????????. ????? ??????? ??? ?? ??? ????? ????? ?????? ?? ??? ?????? ???? (Mao et al.? 2015). WC ????? ???? ???? ????? ???? ????? ?????. ???? ????? Al2O3 ??? ????? ????? ????? ? ???? ????? ????????? ????? ??? ?? WC ????? ? ????? ????? ?????? wc-al2o3. ???? ??????? ???????? ?? ????? 13.6 ?? ?????? ??????????? ?? ????? ??? ??? ????? ????????? ? ???? ????? ??? ????? ??????? ????? ??????? ????????. 

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WC cBN

????? ??? CBN ????? ?????? ?????? ????? ????? ????? ?? ??? ?? ?????? ? ??? ????? CBN ??? WC Co ???? ?? ???? ?????? ?????? ???????? ???????? ??????????? ??????. ????? ????? CBN ?? ?????? WC ? ???? ????? ?????? ???. ???????? ??? ??? ? ???? ?????? ??? ????? ??? ???? ?? ???? ?????? ????? ?? ?? ?????? CBN. ???????? ????????? ?? ????? ????? CBN ??? ??????? ?? CBN ??? hBN ???????? ???????? ????? ??? B ? N ? ??? ???? ??? ?????? ???? ??????? ?? CBN ???????? ????????.

????? WC

????? WC ???? ????? ??? ?????? ? ??????? ??? ?????? ??????? ????????. ???? ????? ??? ?????? ??? ?? ???? ?????????? ???????? ???? ????? ?? ?????? ??? ????????. ?? ???? ?????? ?? ??????? ?????? ???? ??? ?????? ? ?????? ????? ???? ??????? ?????? ? ??? ??? ????? ??????.

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introductionSteel is quenched by heating the steel to a temperature above the critical temperature Ac3 (hypo-eutectoid steel) or Ac1 (hypereutectoid steel), holding it for a period of time so as to be austenitized in whole or in part, and then cooled at a temperature greater than the critical cooling rate Rapid cooling to below the Ms (or Ms near the isothermal) martensitic (or bainite) heat treatment process. The solution treatment of materials such as aluminum alloys, copper alloys, titanium alloys, toughened glass, etc., or heat treatment processes with rapid cooling is also commonly referred to as quenching. Quenching is a common heat treatment process, mainly used to increase the hardness of the material. Usually from the quenching medium, can be divided into water quenching, oil quenching, organic quenching. With the development of science and technology, some new quenching processes have emerged.1 high-pressure air-cooled quenching methodWorkpieces in the strong inert gas flow quickly and evenly cooling, to prevent surface oxidation, to avoid cracking, reduce distortion, to ensure that the required hardness, mainly for tool steel quenching. This technology has recently progressed rapidly and the range of applications has also expanded considerably. At present, the vacuum gas quenching technology developed rapidly, and the negative pressure (<1 × 105 Pa) high flow rate gas cooling followed by gas cooling and high pressure (1 × 105 ~ 4 × 105 Pa) 10 × 105 Pa) air-cooled, ultra-high pressure (10 × 105 ~ 20 × 105 Pa) air-cooled and other new technologies not only greatly enhance the vacuum quenching ability of air-cooled, and quenched the workpiece surface brightness is good, small deformation, but also A high efficiency, energy saving, pollution-free and so on. The use of vacuum high-pressure gas-cooled quenching is the quenching and tempering of materials, the solution, aging, ion carburizing and carbonitriding of stainless steel and special alloys, as well as vacuum sintering, cooling and quenching after brazing. With 6 × 105 Pa high pressure nitrogen cooling quenching, the load can only be cooled loose, high-speed steel (W6Mo5Cr4V2) can be hardened to 70 ~ 100 mm, high alloy hot work die steel up to 25 ~ 100 mm, gold Cold work die steel (such as Cr12) up to 80 ~ 100 mm. When quenched with 10 × 10 5 Pa of high pressure nitrogen, the cooled load can be intensive, increasing the load density by about 30% to 40% over cooling of 6 × 10 5 Pa. When quenched with 20 × 10 5 Pa of ultra-high pressure nitrogen or a mixture of helium and nitrogen, the cooled loads are dense and can be bundled together. The density of 6 × 105 Pa nitrogen cooling 80% to 150%, can be cooled all high-speed steel, high alloy steel, hot work tool steel and Cr13% chromium steel and more alloy oil quenched steel, such as more Large-size 9Mn2V steel. Dual-chamber air-cooled quench furnaces with separate cooling chambers have better cooling capacity than the same type of single chamber furnaces. The 2 × 105 Pa nitrogen cooled double chamber furnace has the same cooling effect as the 4 × 105 Pa single chamber furnace. However, operating costs, low maintenance costs. As China’s basic materials industry (graphite, molybdenum, etc.) and ancillary components (motor) and other levels to be improved. Therefore, to improve the 6 × 105 Pa single-chamber high-pressure vacuum care while maintaining the development of dual-chamber pressure and high-pressure air-cooled quenching furnace more in line with China’s national conditions.Figure 1 high-pressure air-cooled vacuum furnace2 strong quenching methodConventional quenching is usually with oil, water or polymer solution cooling, and strong quenching rule with water or low concentrations of salt water. Strong quenching is characterized by extremely fast cooling, without having to worry about excessive distortion of steel and cracking. Conventional quench cooling to the quenching temperature, the steel surface tension or low stress state, and strong quenching in the middle of cooling, the workpiece heart is still in the hot state to stop cooling, so that the formation of surface compressive stress. Under the severe quenching condition, the supercooled austenite on the surface of the steel is subjected to compressive stress of 1200 MPa when the cooling rate of the martensitic transformation zone is higher than 30 ℃ / s, so that the yield strength of the steel after quenching is increased by at least 25%.Principle: Steel from austenitizing temperature quenching, the temperature difference between the surface and the heart will lead to internal stress. Phase change of the specific volume of phase change and phase change plastic will also cause additional phase transformation stress. If the thermal stress and phase transition stress superposition, that is, the overall stress exceeds the yield strength of the material will be plastic deformation occurs; if the stress exceeds the tensile strength of hot steel will form a quenching crack. During intensive quenching, the residual stress caused by the phase change plasticity and the residual stress increase due to the specific volume change of austenite-martensite transformation. In the intense cooling, the workpiece surface immediately cooled to the bath temperature, the heart temperature almost unchanged. Rapid cooling causes a high tensile stress that shrinks the surface layer and is balanced by the heart stress. The increase of temperature gradient increases the tensile stress caused by the initial martensitic transformation, while the increase of the martensite transformation start temperature Ms will cause the surface layer to expand due to the phase transition plasticity, the surface tensile stress will be significantly reduced and transformed into compressive stress, Surface compressive stress is proportional to the amount of surface martensite produced. This surface compressive stress determines whether the heart undergoes martensitic transformation under compressive conditions or, on further cooling, reverses the surface tensile stress. If the martensitic transformation of the heart volume expansion is large enough, and the surface martensite is very hard and brittle, it will make the surface layer due to stress reversal rupture. To this end, the steel surface should appear compressive stress and heart martensitic transformation should occur as late as possible.Strong quenching test and steel quenching performance: The strong quenching method has the advantage of forming compressive stress in the surface, reducing the risk of cracking and improve the hardness and strength. Surface formation of 100% martensite, the steel will be given the largest hardened layer, it can replace the more expensive steel carbon steel, a strong quenching can also promote uniform mechanical properties of steel and produce the smallest distortion of the workpiece . Parts after quenching, the service life under alternating load can be increased by an order of magnitude. [1]Figure 2 strong quenching crack formation probability and cooling rate relationship3 water-air mixture cooling methodBy adjusting the pressure of water and air and the distance between the atomizing nozzle and the surface of the workpiece, the cooling capacity of the water-air mixture can be varied and the cooling can be uniform. Production practice shows that the use of the law on the shape of complex carbon steel or alloy steel parts induction hardening surface hardening, which can effectively prevent the generation of quenching cracks.Figure 3 water-air mixture4 boiling water quenching methodUsing 100 ℃ boiling water cooling, can get a better hardening effect, for quenching or normalizing steel. At present, this technology has been successfully applied to the ductile iron quenching. Taking aluminum alloy as an example: According to the current heat treatment specifications for aluminum alloy forgings and forgings, the quenching water temperature is generally controlled below 60 ° C, the quenching water temperature is low, the cooling speed is high, and a large residual stress after quenching occurs. In the final machining, the internal stress is out of balance due to the inconsistency of the surface shape and size, resulting in the release of residual stress, resulting in deformed, bent, oval and other deformed parts of the machined part becoming irreversible final wastes with serious loss . For example: propeller, compressor blades and other aluminum alloy forging deformation after machining obvious, resulting in parts size tolerance. Quenching water temperature increased from room temperature (30-40 ℃) to boiling water (90-100 ℃) temperature, the average forging residual stress decreased by about 50%. [2]Figure 4 boiling water quenching diagram5 hot oil quenching methodThe use of hot quenching oil, so that the workpiece before further cooling at a temperature equal to or near the temperature of Ms point in order to minimize the temperature difference, can effectively prevent quenching the workpiece distortion and cracking. The small size of the alloy tool steel die cold 160 ~ 200 ℃ in hot oil quenching, can effectively reduce distortion and avoid cracking.Figure 5 hot oil quenching diagram6 Cryogenic treatment methodThe quenched workpiece is continuously cooled from room temperature to a lower temperature so that the retained austenite continues to be transformed into martensite, the purpose of which is to improve the hardness and abrasion resistance of the steel, improve the structural stability and the dimensional stability of the workpiece, and effectively Improve tool life.Cryogenic treatment is liquid nitrogen as a cooling medium for material processing methods. Cryogenic treatment technology was first applied to the wear tools, mold tool materials, and later extended to alloy steel, carbide, etc., using this method can change the internal structure of metal materials, thereby improving the mechanical properties and processing properties, which is currently One of the latest toughening processes. Cryogenic treatment (Cryogenictreatment), also known as ultra-low temperature treatment, generally refers to the material below -130 ℃ for processing to improve the overall performance of the material. As early as 100 years ago, people began to cold treatment applied to watch parts, found to improve the strength, wear resistance, dimensional stability and service life. Cryogenic treatment is a new technology developed on the basis of ordinary cold treatment in the 1960s. Compared with the conventional cold treatment, cryogenic treatment can further improve the mechanical properties and stability of the material, and has a broader application prospect.Cryogenic treatment mechanism: After cryogenic treatment, the residual austenite in the internal structure of the metal material (mainly mold material) is transformed to martensite, and the precipitated carbide is also precipitated in the martensite, so that the martensite can be eliminated In the residual stress, but also enhance the martensite matrix, so its hardness and wear resistance also will increase. The reason for the increase in hardness is due to the transformation of part of the retained austenite into martensite. The increase in toughness is due to the dispersion and small η-Fe3C precipitation. At the same time, the carbon content of the martensite decreases and the lattice distortion decreases, Plasticity improvement.Cryogenic treatment equipment mainly consists of liquid nitrogen tank, liquid nitrogen transmission system, deep cold box and control system. In the application, cryogenic treatment is repeated several times. Typical processes such as: 1120 ℃ oil quenching + -196 ℃ × 1h (2-4) deep cryogenic treatment +200 ℃ × 2h tempering. After the treatment of the organization there has been the transformation of austenite, but also precipitated from the quenched martensite dispersion of highly coherent relationship with the matrix of ultrafine carbides, after subsequent low temperature tempering at 200 ℃, the growth of ultrafine carbides Dispersed ε carbides, the number and dispersion significantly increased. The cryogenic treatment is repeated a number of times. On the one hand, the superfine carbides are precipitated from the martensite transformed from the retained austenite at the time of the previous cryogenic cooling. On the other hand, fine carbides continue to be precipitated in the quenched martensite. Repeated process can make the matrix compressive strength, yield strength and impact toughness increased, improve the toughness of steel, while making the impact wear resistance was significantly improved.Figure 6 cryogenic treatment device schematicSome of the workpiece on the strict size requirements, does not allow processing due to thermal stress caused by excessive deformation, cryogenic treatment should be controlled cooling rate. In addition, in order to ensure the uniformity of the temperature field inside the equipment and reduce the temperature fluctuation, the design of the cryogenic treatment system should take into account the system temperature control accuracy and the rationality of the flow field arrangement. In the system design should also pay attention to meet the less energy consumption, high efficiency, easy operation and other requirements. These are the current development trend of cryogenic treatment system. In addition, some developing refrigeration systems whose refrigeration temperature extends from room temperature to low temperature are also expected to develop into liquid-free cryogenic treatment systems with the decrease of their minimum temperature and the improvement of refrigeration efficiency. [3]References:[1]樊東黎. 強(qiáng)烈淬火——一種新的強(qiáng)化鋼的熱處理方法[J]. 熱處理, 2005, 20(4): 1-3[2]宋微, 郝冬梅, 王成江. 沸水淬火對(duì)鋁合金鍛件組織與機(jī)械性能的影響[J]. 鋁加工, 2002, 25(2): 1-3[3]夏雨亮, 金滔, 湯珂. 深冷處理工藝及設(shè)備的發(fā)展現(xiàn)狀和展望[J]. 低溫與特氣, 2007, 25(1): 1-3
??????: Meeyou Carbide

First, the molecular beam epitaxial profileIn the ultra-high vacuum environment, with a certain thermal energy of one or more molecules (atoms) beam jet to the crystal substrate, the substrate surface reaction processMolecules in the “flight” process almost no collision with the ambient gas, in the form of molecular beam to the substrate, the epitaxial growth, hence the name.Properties: A vacuum deposition methodOrigin: 20th century, the early 70s, the United States Bell laboratoryApplications: epitaxial growth atomic level precise control of ultra-thin multi-layer two-dimensional structure materials and devices (super-character, quantum wells, modulation doping heterojunction, quantum yin: lasers, high electron mobility transistors, etc.); combined with other processes, But also the preparation of one-dimensional and zero-dimensional nano-materials (quantum lines, quantum dots, etc.).Typical features of MBE:(1) The molecules (atoms) emitted from the source furnace reach the substrate surface in the form of a “molecular beam” stream. Through the quartz crystal film thickness monitoring, can strictly control the growth rate.(2) molecular beam epitaxy growth rate is slow, about 0.01-1nm / s. Can achieve single atomic (molecular) layer epitaxy, with excellent film thickness controllability.(3) By adjusting the opening and closing of the baffle between the source and the substrate, the composition and the impurity concentration of the film can be strictly controlled, and selective epitaxial growth can be achieved.(4) non-thermal equilibrium growth, the substrate temperature can be lower than the equilibrium temperature, to achieve low temperature growth, can effectively reduce the interdiffusion and self-doping.(5) with reflective high-energy electron diffraction (RHEED) and other devices, can achieve the original price observation, real-time monitoring.Growth rate is relatively slow, both MBE is an advantage, but also its lack, not suitable for thick film growth and mass production.Second, silicon molecular beam epitaxy1 basic profileSilicon molecular beam epitaxy includes homogeneous epitaxy, heteroepitaxy.The silicon molecular beam epitaxy is the epitaxial growth of silicon (or silicon-related materials) on a suitably heated silicon substrate by physical deposition of atoms, molecules or ions.(1) during the epitaxial period, the substrate is at a lower temperature.(2) Simultaneous doping.(3) the system to maintain high vacuum.(4) pay special attention to the atomic clean surface.Figure 1 Schematic diagram of the working principle of silicon MBE2 Development history of silicon molecular beam epitaxyDeveloped relative to CVD defects.CVD defects: substrate high temperature, 1050oC, to the doping serious (with high temperature). The original molecular beam epitaxy: the silicon substrate heated to the appropriate temperature, vacuum evaporation of silicon to the silicon substrate, the epitaxial growth.Growth Criteria: The incident molecules move sufficiently to the hot surface of the substrate and are arranged in the form of a single crystal.3 The importance of silicon molecular beam epitaxyThe silicon MBE is carried out in a strictly controlled cryogenic system.(1) can well control the impurity concentration to reach the atomic level. The undoped concentration is controlled at <3 × 1013 / cm3.(2) The epitaxy can be carried out under the best conditions without defects.(3) The thickness of the epitaxial layer can be controlled within the thickness of the single atomic layer, superlattice epitaxy, several nm ~ several tens of nm, which can be designed manually, and the preparation of excellent performance of the new functional materials.(4) Homogeneous epitaxy of silicon, heteroepitaxy of silicon.4 epitaxial growth equipmentDevelopment direction: reliability, high performance and versatilityDisadvantages: high prices, complex, high operating costs.Scope: can be used for silicon MBE, compound MBE, III-V MBE, metal semiconductor MBE is developing.Basic common features:(1) basic ultra-high vacuum system, epitaxial chamber, Nuosen heating room;(2) analysis means, LEED, SIMS, Yang EED, etc .;(3) injection chamber.Figure 2 Schematic diagram of silicon molecular beam epitaxial system(1) electron beam bombardment of the surface of the silicon target, making it easy to produce silicon molecular beam. In order to avoid the radiation of the silicon molecular beam to the side to cause adverse effects, large area screen shielding and collimation is necessary.(2) resistance to heating the silicon cathode can not produce strong molecular beam, the other graphite citrus pots have Si-C stained, the best way is to electron beam evaporation to produce silicon source. Because, some parts of the silicon MBE temperature is higher, easy to evaporate, silicon low evaporation pressure requirements of the evaporation source has a higher temperature. At the same time, the beam density and scanning parameters to control. Making the silicon melting pit just in the silicon rod, silicon rods become high-purity citrus.There are several kinds of monitoring molecular beam:(1) Quartz crystal is often used to monitor beam current, beam shielding and cooling appropriate, can be satisfied with the results, but the noise affects the stability. After several μm, the quartz crystal loses its linearity. Frequent exchange, the main system is often inflated, which is not conducive to work.(2) small ion table, measured molecular beam pressure, rather than measuring the molecular beam flux. Due to the deposition on the system components leaving the standard.(3) low-energy electron beam, through the molecular beam, the use of electrons detected by the excitation fluorescence. The atoms are excited and quickly degrade to the ground state to produce uv fluorescence, and the optical density is proportional to the beam density after optical focusing. Do the feedback control of the silicon source. Inadequate: cut off the electron beam, most of the infrared fluorescence and background radiation will make the signal to noise ratio deteriorated to the extent of instability. It only measured atomic class, can not measure molecular substances.(4) Atomic absorption spectra, monitoring the beam density of doped atoms.With the intermittent beam current, Si and Ga were detected by 251.6nm and 294.4nm optical radiation respectively. The absorption intensity of the beam through the atomic beam was converted into atomic beam density and the corresponding ratio was obtained.Molecular beam epitaxy (MBE) substrate base is a difficult point.MBE is a cold wall process, that is, silicon substrate heating up to 1200 ℃, the environment to room temperature. In addition, the silicon wafer to ensure uniform temperature. Hill resistance refractory metal and graphite cathode, the back of the radiation heating, and the entire heating parts are installed in liquid nitrogen cooled containers, in order to reduce the thermal radiation of the vacuum components. The substrate is rotated to ensure uniform heating. Free deflection, can enhance the secondary implantation doping effect.
??????: Meeyou Carbide

1, Review of Organic Halide Perovskite – related Photoelectric PropertiesFigure 1 Spectral position and PL peakOrganic halide perovskites are widely used in optoelectronics research. Methyl ammonium and formamidine lead iodide as photovoltaics show excellent photoelectric properties and stimulate researchers’ enthusiasm for light-emitting devices and photodetectors. Recently, the University of Toronto Edward H. Sargent (Correspondent) team of organic metal halide perovskite optical and electrical properties of the material were studied. Outlines how material composition and form are associated with these attributes, and how these properties ultimately affect device performance. In addition, the team also analyzed different material properties of the perovskite materials, in particular the bandgap, mobility, diffusion length, carrier lifetime and trap density.The Electrical and Optical Properties of Organometal Halide Perovskites Relevant to Optoelectronic Performance（Adv.Mater.,2017,DOI: 10.1002/adma.201700764）2, Advanced Materials Overview: 2D optoelectronic applications of organic materials Figure 2 Several key steps in the application of two-dimensional organic materialsThe 2D material with atomic thin structure and photoelectron properties has attracted the interest of researchers in applying 2D materials to electronics and optoelectronics. In addition, as a two-dimensional material series of emerging areas, the organic nanostructure assembled into 2D form provides molecular diversity, flexibility, ease of processing, light weight, etc., for optoelectronic applications provides an exciting prospect. Recently, Tianjin University, Professor Hu Wenping, Ren Xiaochen assistant researcher (common newsletter) and others reviewed the application of organic two-dimensional materials in optoelectronic devices. Examples of materials include 2D, organic, crystalline, small molecules, polymers, self- Covalent organic skeleton. The application of 2D organic crystal fabrication and patterning technology is also discussed. Then the application of optoelectronic devices is introduced in detail, and the prospect of 2D material is briefly discussed.2D Organic Materials for Optoelectronic Applications（Adv.Mater.,2017,DOI: 10.1002/adma.201702415）3, Advanced Materials Review: 2D Ruddlesden-Popper Perovskite PhotonicsFigure 3 Schematic diagram of 3D and 2D perovskite structuresThe traditional 3D organic-inorganic halide perovskite has recently undergone unprecedented rapid development. However, their inherent instabilities in moisture, light and calories remain a key challenge before commercialization. In contrast, the emerging two-dimensional Ruddlesden-Popper perovskite has received increasing attention due to its environmental stability. However, 2D perovskite research has just started. Recently, the University of Fudan University, Liang Ziqi (Corresponding author) team published a review first introduced 2D perovskite and 3D control of a detailed comparison. And then discussed the two-dimensional perovskite organic interval cationic engineering. Next, quasi-two-dimensional perovskites between 3D and 2D perovskites were studied and compared. In addition, 2D perovskite unique exciton properties, electron-phonon coupling and polaron are also shown. Finally, a reasonable summary of the structure design, growth control and photophysics research of 2D perovskite in high performance electronic devices is presented.2D Ruddlesden–Popper Perovskites for Optoelectronics（Adv.Mater.,2017,DOI: 10.1002/adma.201703487）4, Science Advances Summary: Lead Halide Perovskite: Crystal-Liquid Binary, Phonon Glass Electronic Crystals and Great Polaron FormationFigure 4 CH3NH3PbX3 perovskite structureLead anodized perovskite has proven to be a high performance material in solar cells and light emitting devices. These materials are characterized by the expected coherent band transport of crystalline semiconductors, as well as the dielectric response and phonon dynamics of the liquid. This “crystal-liquid” duality means that lead halide perovskites belong to phonon glass electron crystals – a class of thermoelectric materials that are considered to be the most efficient. Recently, the University of Columbia Zhu Xiaoyang (communication author) team reviewed the crystal-liquid duality, the resulting dielectric response responsible for the formation and selection of carrier polaron, which causes perovskite with defect tolerance, moderate Of the carrier mobility and the combined performance of the radiation. Large polaron formation and phonon glass characteristics can also explain the significant reduction in carrier cooling rates in these materials.Lead halide perovskites: Crystal-liquid duality, phonon glass electron crystals, and large polaron formation（Sci. Adv.,2017,DOI:10.1126/sciadv.1701469）5, Progress in Polymer Science Review: Lithography of silicon-containing block copolymersFig.5 Melt phase diagram of diblock copolymerRecently, the National Tsinghua University Rong-Ming Ho (Correspondent) and others published a summary of the different methods through the preparation of ordered block copolymer (BCP) film the latest progress, focusing on the use of silicon-containing BCP as lithography applications. With the advantages of Si-containing blocks, these BCPs have smaller feature sizes due to their high resolution, large segregation intensity and high etch contrast. Considering that poly (dimethylsiloxane) (PDMS) has been extensively studied in Si-containing BCPs, the possibility of photolithography using PDCP-containing BCP has been demonstrated through previous and ongoing studies. Subsequent sections detail the main results of the DSA approach. The new trend of lithographic printing application and the application of photolithography nano – pattern using silicon – containing BCPs are also discussed. Finally, the conclusion and prospect of BCP lithography are introduced.Silicon-Containing Block Copolymers for Lithographic Applications（Prog. Polym. Sci.,2017,DOI:10.1016/j.progpolymsci.2017.10.002）6, Angewandte Chemie International Edition Overview: CH3NH3PbI3 perovskite solar cell theoretical studyFigure 6 Electronic density patternPower conversion efficiency (PCEs) of more than 22% of the hybridized perovskite perovskite solar cells (PSCs) has attracted considerable attention. Although perovskite plays an important role in the operation of PSCs, the basic theory associated with perovskite remains unresolved. Recently, Professor Xun Nining (Communication Author) of Xi’an University of Architecture and Technology, according to the first principle, evaluated the existing theory of structure and electronic properties, defects, ion diffusion and transfer current of CH3NH3PbI3 perovskite, and ion transport Influence on PSC Current – Voltage Curve Hysteresis. The moving current associated with the possible ferroelectricity is also discussed. And emphasizes the benefits, challenges and potential of perovskite for PSCs.Theoretical Treatment of CH3NH3PbI3 Perovskite Solar Cells（Angew. Chem. Int. Ed.,2017,DOI: 10.1002/anie.201702660）7, Chemical Society Reviews Overview: Reductive Batteries for Electromechanical Active Materials for Molecular EngineeringFigure 7 Molecular engineering for redox substances for sustainable RFBAs an important large energy storage system, redox batteries (RFBs) have high scalability and independent energy and power control capabilities. However, conventional RFB applications are subject to performance and limitations on high cost and environmental issues associated with the use of metal-based redox substances. Recently, the University of Texas at Austin Guihua Yu (communication author) team proposed the design of these new redox substances system molecular engineering program. The article provides a detailed synthesis strategy for modifying organometallic and organometallic redox substances in terms of solubility, oxidation-reduction potential and molecular size. And then introduced recent advances covering the reaction mechanism of the redox species classified by its molecular structure, the specific functionalization methods and electrochemical properties. Finally, the author analyzes the future development direction and challenge of this emerging research field.Molecular engineering of organic electroactive materials for redox flow batteries （Chem.Soc.Rev.,2017,DOI: 10.1039/C7CS00569E）8, Chemical Society Reviews Overview: Atomic level for energy storage and conversion Non-layered nanomaterialsFigure 8 Atomic-grade layered and non-layered nanomaterialsSince the discovery of graphene, the two-dimensional nanomaterials with large atomic thickness and large lateral dimension are highly studied because of their high specific surface area, heterogeneous electronic structure and attractive physical and chemical properties. Recently, Wulonggong University Dushi University academician (communication author) team comprehensively summed up the atomic thickness of non-layered nano-materials preparation method, studied its heterogeneous electronic structure, the introduction of electronic structure operation strategy, and outlined its energy storage and conversion Applications, with particular emphasis on lithium-ion batteries, sodium ion batteries, oxygen, CO2 reduction, CO oxidation reaction. Finally, based on the current research progress, put forward the future direction – in practical application to enhance the performance and new features to explore.Atomically thin non-layered nanomaterials for energy storage and conversion （Chem.Soc.Rev.,2017,DOI:10.1039/C7CS00418D）9, Chemical Reviews Overview: Electrochemical Applications in the Synthesis of Heterocyclic StructuresFigure 9 Mechanism of electro-induced cationic chain reactionThe heterocycle is one of the largest organic compounds to date, and the preparation and transformation of heterocyclic structures have been of great interest to organic chemistry researchers. Various heterocyclic structures are widely found in biologically active natural products, organic materials, agrochemicals and drugs. When people notice that about 70% of all drugs and agrochemicals have at least one heterocycle, people can not ignore them importance. Recently, Professor Zeng Chengchao of Beijing University of Technology (Correspondent Author) team reviewed the progress of electrochemical construction of heterocyclic compounds published by intramolecular and intermolecular cyclization since 2000.Use of Electrochemistry in the Synthesis of Heterocyclic Structures（Chem. Rev.,2017,DOI:10.1021/acs.chemrev.7b00271）
??????: Meeyou Carbide

????? ? ????? ????? ???? ??????? ??????: 1945 - 1951 ? ?????? ?????? ?????????? ?????? ???? ?????? ?????? ????????? ??????: ???? (????? ???????? ? ???? ?? ????? ?????? ?????) ??????? (????? ??????? ? ???? ?? ????? ?????? ?????????) ??? ??? ?????? ????. ??????? ???????: 1951 ??? 1960 ????? ?????? ? ???? ????? ?? ??? ??????????? ?????? ??????? ? ??? ?????? ?? ??????? ??????. ??? 1953 ?? ??? ????? ???? ???????? ???? 30 ???? ????. 1958 ?????? ???? 60MHz ? 100MHz ????. ?? ????? ?????????? ? ?? ????? 1H-NMR ? 19F-NMR ? 31P-NMR ??????? ???????: 60 ??? 70 ????? ? ???? ???? ????? NMR. ???? ????? ????????? Pulse Fourier ?????? ???????? ??????? ???? ?????? ??? ???? 13C ???? ? ????? ?????? ????? ?????? ?????? ???????? ? ??????? ???????: ????? ?????????? ?????? ??????????? ????? 1200 ? 300 ? 500 ???????? ? 600 ???????? ????? NMR ???? ??????? ? 2 ? ????? ?????? ?????? ?? ????? ????? ? ?? ??????? ????? ??????? ? 3 ? ??? 2D-NMR ? 4 ? ??? ????? ?????? ? ???? ?????? ??? ???? ????? ??????????? ? 5 ? ???? ???? "????????? ??????? ??????? ?????????? ??????" ?????? ?? ???????? ??????? ???????. ?????? ? ????? ???????: 1. ????? ?????? ?????? ? ????? ?? ??? ??????? ????? ??????? ???????? 2. ??? ???? ???? ? ?????? ??? ? ????????????? ????? ????? 3. ????? ?????? ? ??? ??????? ???????? ?? ?????? ? ???? ??? ???? ?? ???? ???? ??????. ??????? ????????? ? ?????? ??????? ??????? ? ?????? ?????? ????????? ?????????? ?????? ?? ???? ???????? 1. ???? ?????? ?? ????? ???? ??????? ? ?????? ??? ????? ??? ???? ?????. ??? ????? ???????? ?? ????? ?????? ?????????? ??????. Spin Quantum: ??? ??????? ???????? ???? ??? ?????? ????????? ?????? ? ????? ???? ?? ???? ????? ?????? ?? ????? ?????? ?? ????? ? ??? ????? ?????? ?????? ? C ? H ? O ? N ?? ?????? ?????? ?????. ?? ??????? ? 12C ? 16O ?? ??? ????????? ???????? ?? ???? ????? ???????? ????. 1H ???? ?????? ????? ? ????????? ???? ? ???? ??????? ? ???? ???? ????? ?????? ?????????? ?????? ???? ????? ????????. ???? 13C ????? ? ??? 12C 1.1% ? ??????? ??????? ???? ??? ?????? ?????? ??? 1/64. ??? ??? ???????? ????????? 1/6000 ??? ?? 1H ? ???? ????? ?? ???????. ???? ?? ???????? ????? ??????? ? ?? ????? ???? ?????? ?????????? ?????? ???? ???? ? ????? ?????? ?? ???? ????? ????? 13C ? ?????? ?????? ?? ????????? ? ????? ??????? ???????? ?????? ?????????? ??????. 1H ? 19F ? 31P ???? ?????? ?????? ?????? ??????????? ??????? ??????? ???????? ??????? ? ?????? ????? ?? ???????. ????? ?????? ?????????? ?????? ① ?????????: ???? ?? ???? ????????? ????? ??? ????? ?????? ?????????? ??????? H0 ? ????? ??? ?????? ????? ?????? ??????????: ?? ?????? ?????????? ??????? ? ????? ?????? ?? H0 (??? ?????? ?????????? ???????) .② ??????? ?????? ?? ????? ?????? ?????????? ???????: ?? ???? ???? ???????? ????? ? ??? ??????? ??????? ?????????? ?? ?????. ???? ????? ?????????? ?? ?????? ?????????? ??????? H0 ? ?? ????? (2I + 1). ???? ?? ???? ????? ?????? ??????????? ?? ?????? ?????????? ??????? ??????? ?????? (????? ? ???????) ?????????? ?? ???? ????????. ③ ???? ?????? ?????????? ?????? ??? ?? ????? ?????? ?????????? ?????? ?????????? ??? ????? ??????????? ? ?????? ?????????? ??????? ??????? ?????????? ???????? ?????????. ????? ?????? ?????????? ???????? ????????? ????? ?????? ?????? ????? ?????? ? ????? ?????? ?? ???? ?????? ???????? ??? ???? ?????? ???????. phenomenon ????? ?????? ?????????? ??????: ?? ??????? ??????? ?????? ?????????? ??????? H0 ? ??? ????? ???? ???????? ???? H1 ??? ???? ????????. ??? ??? ?????? ???????? ?? H1 ??????? ????? ????????? ???????? ?????? ? ????? ?? ???? ???? ?????? ?????? ?? H1 ????????? ?? ???? ?????? ???????? ??? ???? ?????? ??????? ?????? ?????????? ??????. ?????? ?????????? ?????? ??????? ?????? ??? 0.001% ???? ?? ?????? ??????? ???????. ???? ? ??? ???? ???? ?????? ???????? ?????? ?? ???? ???? ?? ?????? ??????? ??????? ? ??? ??? ??? ?????? ?????? ? ???? ???? ?????? ?????? ??????? ???????????????. ??? ??? ???????? ?????? ??????? ??????? ??????????????? ? ??? ????? ???? ?????? ???????? ??????? ???????? ? ???? ???? ??? ????? ???????? ? ?????? ?????? ?? ??????? ? ????? ??? ??????? ??????. ????? ???? ?????? ? ???? ??? ????? ?? ????? ??????? ?? ???? ??????. ?? ?????? ?????????? ??????? ? ???? ????? ?????? ?????? ???? ??? ???? ????? ?? ???? ?????? ??????? ? ????? ???? ??????? ??????????????? ?????? ??? ???? ?????? ??????? ?????? ????? ??????? ?? ???? ?????? ?????? ?? ????? ?????? ? ? ???? ??? ???? ?????? ???????? ??????? ? ??? ??????? ???? ?????????. ????? ????? - ?????? ????????? - ?????? ???????? ?????? ?????? ??????? ???????? ΔE = (h / 2π) γ · H ? ??? H0 ????? ? ???? ?????? ΔEΔE = E ???? = hν ??? ?????? ?????? ν ???????? ??? H0 = 2.3500 T ? ???? ?????? 1H ?? 100 MHz ? ???? ?????? 13C ?? 25.2 MHz② ?????? ????????: ????? ??????? ??????? ???? ????????? (??? ?????? ? ??? ??????) ?? ????????: ????? ???????? ??? ?????? (???) ? ??? ??????? ?????????? ? ????? ?????????? ? ????????? ???????????????? ? ????? ??? ???????? ????: ?? H0 = 2.3500 T ? ???? ??????????? ???????? ????? ? ?? ????? ?????? ? ???? ?????? ?????????? ??????? ???? ?????? ?? 2.3500 ???? TResonance ???? ????? ?? 100 MHz ?? ??? 1H ?? 0 ??? 10 ? ? 13 C ?? 0 ??? 250 ? ??? ??? ?????????? ????? ??? ????????? ?? ?????? ? ????? ??? ???? ?????? ?????????? ?????? ??????????. ??????? ?????? ? ???? ??????????? ??????? ????? (?????). ???? ???? ????? ????? ????????? ??? ?????? ? ??? ????? ??????? ? ???????? ???????? ?? ??? ?????? ?????????? ????? ???. ????? ????? ??????? ??????????? ??? ?????? ?????????? ??????? ? ???????? ??? ??? ??????? ?????????? ???????? ? ????? ?? ??????? ??? ?????? ? ??? ???? ?????? ?????? ?????????? ?????? ?? ????? ??????. ③ ??? ?? ???? ?????? ????? 60 ???? ???? ?? ???? 100 ???? ???? ? ???? ??????? ??????????????? ???????? ?????? ?????? ????? 1000 ???? ?? 1700 ????. ?? ????? ?????? ? ????? ?????? ??? ????? ???? ?????? ?????? ?? ???? ?? ??????? ??? ??? ???? ? ???? ??? ?? ?????? ??????? ?????? ?????? ?????? ??????. ???? ????? ??? ???? ?????? ?????? ??????? ????? ?????? ???????? ?????? ?????????. ??????? ??????? ?????? H NMR ??? ????????: ?? ??? ??????? ???????? ?? ?????????? ???????? ?? ?????? ???? ???????: ?????? ??????????? ??? ?????? ? ?????? ????????? ??? ???????: ??? ?? ??? ?? ?????? ???? ????????: ?? ???? ???????? ??????: ?????? ????????? ??????? ??????? ?? ???????? ??????? - ??????? ??????? - ??????? ???????? - ????? ???????? ???? ?? ???? ?????? ????????? ???? ????? "???????????" ????? ?????? ?????? ?? ????? ????? ?????? ????????? ?? H ???? ????? ???????????? pi ? ????? ??? ???????????? H H ??????? ??????? ROH ? RNH2 ?? 0.5-5 ? ArOH ?? 4-7 ? ??? ??????? ? ????? ?????? ?? ??????? ? ??????? ??????????? ?? ???? ???? ??????? ? ?????? ? ??????? ???? ????? ? ????? ??? ?????? ????????? ???????? ???????? ????????????. effect ????? ?????? ???? ??????? ?????? ?? DMF. ???? ????? ????????? ?? ???? ??????? ?????? ???????? ?? DMF ? ????? ?????? ??????. ???? ????? ???? ?? ????? ??????? ? ????? ?????? ??? ?????? ??????? ? ? β ??????? ?? ????? ??????? ? ????? ?????? ?????? ??? ?????? ??????? ? ???????? ?? ?? ???? ???? ???????? ????????.
??????: Meeyou Carbide

????? ? ??????? ??????? ?????? ??? ???????? (1) ????????: ?? ??? ???? ???? ??????? ??????? ? ?? ?????? ???????? ?????? ???????. ??? ???? ???? ? ????? ????? ????? ????? ??? ?????? ?? ???????? ??????? ? (2) ??? ????????: ??? ???????? ? (3) ????? ??? ????????: ????? ????? ???? ????? ?? ?????? ??? ???????? ???????? ? ??? ??????? ? ?????? ??????? ??????? ????? ? (4) ????? ????? ??? ????????: ????? ?????? (??????? ?????? ???????? ????????) ? ??????? ???????? ? ????? ??????? ? ??????? ??????? RR ? ??????? ??????? ? (5) ??? ????????: ??? ???????? ? ???? ????????? ????? ? (6) ??? ?????? ???????: ????? ???? ???? ?? ?????? ?????????? ????????? ??????? ????????? ??????? ?? ??????? ? ?????? ???????? ??????? ????????? ?????? ??? ???????? ??????? ? (7) D10 ? ??????? ???????? ?? 10% ?? ??? ???????? ??????? ? D50 ? ??? ??????? ???????? ?????? 50% ?? ??? ???????? ??????? ? ????? ????? ???? ????? ??? ???????? ?????? ? D90 ? ??? ??????? ???????? ?????? 90% ?? ??? ???????? ??????? ? D (4?3) ??? ?? ????? ??? ???????? ? ?????? ? ????? ???? ??? ???????? ????? ????????? (1) ????? ??????? (2) ????? ??????? (????? ??????? ????????? ? ????? ??????? ?????? ???????) (3) ????? ???????? (???? ???????? ???? ) (4) ????? ?????? (??????) (5) ?????? ?????????? (6) ????? ??????? ??? ??????? (7) ????? ?????? (8) ????? ???? ?????? ????? ????? ????? ???????? ????? ??????: ???????: ????? ? ????? ? ????? ?????? ??????? ? ????? ????????? ?? ????? ???? ?? 40 ????????. ??????: ?? ???? ????????? ????? ????? 40μm ? ????? ??????? ??????? ????? ??????? ?? ????? ????.??????: ???????: ????? ? ?????? ? ???? ?? ???? ??????? ??????. ??????: ????? ? ????? ??????? ? ?? ???? ???? ???????? ??????? ??????.????? ??????? (??? ?? ??? ????? ???????? ?????? ????? ???????): ???????: ????? ??????? ? ???? ?????? ????? ???? ????? ? ??????? ????? ?????? ???????? ???? ? ???? ???????? ????. ??????: ??? ???????? ????. ????? ????????: ???????: ??? ??????? ? ???? ???? ????? ???????? ???????? ? ??????? ??????? ???? ? ???? ? ??? ????. ??????: ???? ???????? ???? ???? ???? ????????? ? ??? ?? ???? ??????? ????? ???????? ?????.??????????? ??????????: ???????: ?????? ??????? ?????? ??????? ????? ?? ??? ?????? ?????? ? ????? ?????. ??????: ???? ??? ? ????? ???? ? ?????? ?????. ??????? ??? ???????: ???????: ?????? ??????? ????????? ??????? ?? ????. ??????: ??? ??????.????? ???????: ???????: ????? ??????? ?????? ? ?? ????? ???? ????? ?????? ? ???? ???? ???????? ???????????. ??????: ???? ??? ?????? ??? ????? ??? ???????? ? ??? ???? ???? ????? ??? ????????. ????? ??????: ???????: ????? ??????? ? ???????? ?????? ? ???? ???????? ? ??????? ?????? ? ????? ?????? ??? ???????? ???????. ??????: ??????? ???????? ?????? ??????? ? ???? ?????? ????? ?????? ? ?????? ? ??? ?????? ??????? ????? ??? ???????? ??????? ?????? ???? ?????? ?? ???? ??????? ??????? ? ??? ??? ??? ??????? ????? ????? ????? ??????: ????? ???? Fraunhofer ( ???????) ????? ???? ????? ???????????? ???? ?????? ??????? (LALLS) ?? ????? ?????? ? ?? ????? ??? ?????? ?? ??????????? ????? ???? ????? ?? ???? ???? ?? ??????? ? ???????? ??? ??????? ????????? ??? ???? Fraunhofer ??????? ??? ??????? ? ? ?????? ????? ????? ??????? ???? ????? Mie ?????? ?? ??????? ?????? ????????? ? ??? ???? ????? ???? ??? ??? ???? ??????. ??? ???????? ??????? ???????? ?? ????? ??????? ??? ?????? ?????? ?? ????? ??????? ? ????? ?? ???? ???????? ????? ?????? ?? ???? ???????? ???????. ??? ????? Millerian ?? ???? ????? ?? ????? ????. ??? ???? ??? ???? ???? ?? ?????? ?????? ? ??? ?????? ???? ???????? ?????????????? ??? ??? ???? ???? ????? ??????? - ??? ????? ?? ??? ???? ????? ???? ?????? ????? ???????? ???????? ???????. ??? ??? ???????? ?????????? ??? ??? ???? ???? ? ???? ????? ????? ?????? ??? ????? ???? ????? ???? ????? ????. ????? ?????? Mie ? ?? ?????? ????? ??????? ?????? ?????????? ???????? ? ????? ????? ????? ??? ?????? ?????? ????? ?????? ???? ???????? ???? ???? ????? ????? ???????? ???????? ??????? . ??? ??? ?????? ????? Mie ? ??? ?? ???? ???? ???????? ?????? ???????? ?????? ??????? ? ??? ?? ????? ????? Fraunhofer ??? ??? ????????? ???????? ? Franco ? Fader ? ????? ????? ??? ?????? ??? ???? ?????? ????? ??? ??? ?????? ??? ?????? ????? ?????? ?????? ???? ?????. ????? ???? ??? ???????? ??? ?? ????? ?????? ?? ?????? ? ??? ?????? Fraunhofer ??? ????? ???????? ???? ?? ??? ?????? ??????? (??? ????? ?????? Mie ? ?? ????? ????? Mi ?? ??????? ????? ????? ?????? ????? ????? ???????? ?????? ???????? ? ?? ?? ???? ???????? ??????? ??????? ???????? ??? ??????? ??? 1 ? ????????? ???????? ???? ????? ? ???? ?????? ????????? ??????? ?? ????? ??? ???? ?????. ????? ???? ????????? ?? ????? ??? ????????). ????? ???? ??? ?????? ?????? ??? ????? ???? ????? ? ????? ????? ?? ???? ???????? ??? ????? ?????? (?????? ?? ????? ??????? ??????????????? ???????). ?????? ????? ????? ??????? ???? ???? ?? ??? ??????.????? ?????? ?? ???????? ??? ???? ?????? ????? ???? ??? ???????? ?? ????? ?????? ? ???? ??????? ?????? ??? ?????? ? ??? ???????? ??????? ?? ???? ???? ?????? ????? ???? ??? ???????? ?? ??? ??????. ???? ??????? ??? ????? ??????? ?????? ??????? ???????? ?? ??? ????? ?? ?????? ? ??????? ????? ???? ?????? ????? ?? ????? ????? ?????? ????? ??? ????? ??????? ?? ????? ?????? ?? ??? ?????? ? ???????? ????? ???????? ? ?? ???? ???????? ??????? ? ?? ????? ??? ???????? ?????? ? ????? ??? ????? ???????? ???? ??????? ???? ?????? ???? ????? ?? ??? ?????? ??????? ? ?????? ?????? ??? ????? ??????? ??? ???????? ???? ?? ?????? ??? ????????. ????? ???? ???????? ????? ??? ??? ???? ?? ????????? ? ??? ??? ???????? ????? ???? ???? ??????? ??? ??????? ? ?? ?? ????? ??????? ?? ??? ????? ??? ?????? ?? ?????? ????? ?? ??????? ? ????? ??? ????? ??? ???? ????? ????? ???? ? ??? ???? ?? ????? ?????. ?? ???? ??????? ??? 1um ??????? ??? ???????? ??????? (????? ????????? ??? ??? ???? ????????) ?? ??????? ????? ??????? ???????. ???? ??? ? ??? ??????? ???????? ??????? ???????? ?????? ??????: 1 ? ????? ??????? ???????? ?? ?????? ?????? ????? ??????? ??? ???? ???? ??? ??????????? ? ???????? ????? ???? ???? ?????? ? ??? ?? ??? ???? ?????? ???? ???? ??????? ? ????? ???? ?? ??????? ??????? ???????? ?????? ???????? ?????? ??? ???????? ????????. ?????? ?? ????? ???? ? ????? ??? ??? ??????? ?? ????? ????? ???? ???? ??????? ?????? ? ??????? ??????. ????? ?? ??? ??? ??? ??? ?????? ?????? ??? ?????? ??? ??????? ?????? ? ???? ????? ????? ??????? ???????? ? ??? ???? ??? ??? ???????? ??? ???????? ?????? ?? ???? ?????? ??????? ?? ???? ????????? ?? ??????? ?? ???? ????????? ?? ??? ?????? ?? ???? ?? ???? ?? ????? ??????? .2 ? ????? ??????? ?????????????? ????? ???? ????? ??????? ????? ?? ????? ???? ???? ?????? ???? ??? ????? ???? ?????? ???? ???? ??????? ? ???? ??? ??? ?? ???? ????? ????? ???? ??????? ? ?? ??? ????? ????? ????? ??????? ? ???? ???? ?????? ??????? ???????? ??????? ????? ??????? ??????? ? ??????? ?? ?????? ????? ?? ?????? ?????? ?????? ??????? ?????? ?????? ????? ????? ?????. ???? ??? ??????? ?? ???? ???? ???? ??? ?????? ??? ??? ????? ?? ??????? ? ???????? ??????. ???? ?? ???? ???? ?????? ? ????? ???? ?????? ? ??????. ????? ?? ?? ???? ??????? ??????? ?????? ?? ???? ??????? ??????? ?????? ????? ????? ???????? ??????? ? ???? ???????? ??????? ????? ??????? ?? ????? ???? ??????? ????? ? ??? ???? ??? ?????? ????? ????? ???? ???? ??????? ??? ??????? ??? ????? ? ???? ?? ????? ?? ?? ???? ???? ????? ??????? ?? ???? ?????? ???? ?? 1500 ?????? ?? ??? ??? ? ????? ?? ???? ???????? ???????? ??????? ??????? ?? ?????? ?????? ? ??????? ??? ??????? ????? ?????? ?????? ????? ??????? . ???????? ??? ??? ? ??? ?????? ????? ??????? ?? ???? ??????? ? ??? ????? ????? ?????? ???????? ? ??? ?????? ????? ? ??? ???????? ?? ???? ?? ??? ??? ?? ???? ?????? ??????? ? ???? ??????? ???? ??? ???? ??? ?????? ? ???? ????????? ????? ?????? ??????? ???????? ???? ?????? ????? ????? ??? ?? 250 ??????? 3 ? ???? ???? ????? ????? ???? ?????? ?????? ????? ????? ??? ????? ???? ?????? ???? ???? ?????? ????? ????? ??? ???????? ? ?????? ??? ?????? ?? ??????? ??? ??? ????? ?? ????? ????? ????? ? ?? ?????? ???? ???? ??? PCS ? ?????? ???? ???????? ???? ????? ??????? ??????? ? ???? ???? ???????? ??? ???? ?????? ???? ????. ?? ??????? ??????? ? ????? ???? ?????? ???? ???????? ??? ???? ?????? ??????? ????????. ???? ??? ??????? ?? ?? ??????? ?????? ??? ???? ?????? ????? ???? ? ????? ???? ?????? ???? ??????? ??????? ? ??? ????? ?????? ???? ?? ????? ? ?????? ?? ???? ?? ????? ????? ??????? ? ???????? ??? ????? ??????? ??? ????? ???????? ? ?????? ?? ???? ?? ????? ?????? ??? ??????? ??????? ?? ????? ?????? ???????? ????????? ?? ?? ??? ??????? ?? ??? ???? ?????? ??? ??? ?? ???? ????? ?????? ?? ???? ?????? ?? ??????? ????????. ???????? ??? ??? ? ????? ???? ????? ????? ???????? ?????? ???? ???????? ? ??? ?? ???? ????? ?????? ????? ???? ???? ????? ????? ?????? ? ???? ?? ???? ????? ?????? ??? ?? ???? ???? ?????? ?????? ???? ? ????? ?????? ???????? ? ??? ??? ?????? ?????? ?? ???????? ???????? ?? ?????? ????? ???? ?????? ???? ???????? ???? ?? ???? ??? ???? ????????? .4 ? ???????? ??? ??????? ??? ???? ???? ?????? ????? ?????? ????? ????? ???? ???? ??????? ?? ????? ????? ?? ??????? ?????? ??????? ??? ???????? ??? ???? ???? ??????? ?????? ?????? ?? Fourier ?? ????? ?????????. ??? ??????? ????? ?????? ?????? ?????? ?? Fourier ???? ?????? ??? ???? ??????? ? ?? ?????? ????? ???? ?? ??????? ? ????? ????? ?????? ?????? ??? ??? 150 ???? ? ???? ???? ????? ????? ????? ????????? ??? ??? ???? ?????? ?????? ???? ? ???? ?????? ???? ???? ?? ????? ?????? ??? ??????? ?????? ??? ??????? ??? ????? ??? ????? ?????? ??? ????? ??????? ? ??? ?? ???? ????? ??? ???????? ??????? ??? ???? ?????? ????? ????? ????? ????? ?? ???????? ????? ??????? ?????????. ?? ???? ???????? ?????? ????? ???? ????? ?????? ?? ????? ????????? ??? ??? ???? ?? ?????????? ?? ???????? ? ??? ?????? ????? ? ???? ?? ??? ???? ?????? ??? 0.1 ??????. ??? ??? ????? ?? ?? ????? ?????? ????? ??????? ????? ??????? ? ??? ??? ????? ???? ?????? ??????? ?? ?????? ?????? ?????? ? ????? ????? ? ?????? ???????? ? ?? ???? ???? ???? ???? ????? 10 ?? ? ??? ????? ?????? ??? ???????? ?????? ?????? ? ????? ??? ?? ????? ? ????? ????? ? ???????? ??? ?????? ?????? ??????? ??????????. ????? ??? ???? ??????? ?????????? ??? ??????? ?????? ????? ?????? ? ??? ?? ???? ??? ?????? ?????? ?? ????? ???? ?????. ????? ?????? ????? ????? ?? ??????? ?????????? ?? ????? ?? ??????? ??????? ?????? ? ?? ???? ????? ?? ???? ????? ???? ??? ????? ????? ???????? ?????? ??? ?? ??? ??? ??? ??? ?? ?????? ??? ????? ?????? ??? ???????? ???? ???? ??????? ?????????? ?? ???????? ? ??? ??????? A / D ??? ????????? ? ????? ???? ?????? ??????? ????? ??? ?????? ?????? ?????? ?????? ? ???? ??? ?????? ? ?? ????? ?????? ? ???? ????? ??? ??????????? ???????: (1) ???? ??? ?? 1 ??? ?? ???????? ? ??? ???? ??????? ????? Mie ? (2) ???? ???? ?? 1mm ?? ???????? ? ??? ??? ???? ?????? ????? ?????? ??? ?? 3mm ? ??? ?????? ?? ???? ?????? ????? Mie ? ?? ?? ????? ??? ???????? 1 ?? ?????? ?? ?????? "?? ?? ???" ? (3) ???? ????? ??? ?????? ?????? ??????? ????? ?????? ??????: ???? ?????? ????? ?????? ???? ?? 3 ?? ? ?? ???????? ??????? ??? ??? ? ???? ???????? ???? ?? 1 ?? ? (4) ????? ????? ???? ?????? ?????? ? ????? ?? ???? ?????? ?????? ??? ?? 1 ?? ? ???? ?? ???????? ????? ???????? ??????? ?? ???????? ??????? ? ??? ??????? ????? ?? ? ?????? ? ??? ????? ?????? ???? ??? ?????? ?????? ??? ??????? ???? ??? (???? ????) ?????? ???? ????? ????? ??????? ??????? ? ???? ?????? ?????? ?? ???? ???? ???? ????? ????? ???? ?????? ?? ???? ????? ??????? ??? ???????? ?????? ???????? ??????? (???? ??? ??? ?????? ?? ??? ???? ???? ? ???? ??? He-Ne (λ = 0.63 ??). ???? ???????? (????? ??????) ???? ??? ?????? ?????? (??? ???? ?? ????????? ???????) ????????? (?????? ?? ??????? ????? ????? ??? ????????) ?? ???? ?????? ?????????? ? ???? ?? ???? ???? ?????? ?????? 0.1um ? ???? ?? ??? ??? 0.02umSix ? ?????? ????? ???????? 1 ? ?????? ??????? ?????? ?????? ?????? (?????) 2 ? ???? ?????? ? ???????? ? ??????? ?????? ?????? ????? ?? ???? ??? ???????? ???? ???????? ??? ??? ??? ?????? ?????? ? 3 ? ?????? ( ??? ??????? ?????? ???????) 4 ? ????? ?? ?????? ???????? ???? ?????? (????????) ? ???? ?? ???? ?? ????? ?????? ??? ?????? ? ????????? ?? ???????? ?????? ? ?? ???????? ? / ?? ???? ??????? ???????? ??? ???????? ?????? ???? ????? ???? ? ???? ? ??????? ??????? ?????? ???? ??? ???????? ??????? ????? ????????????? ??? ???????? ??????? ????????? ??????? (?? ??????) ?????? ????????? ??????? ???? ?? ???? ??? ???????? ??????? (Zhuhai) Dandong ???? ??? ???????? ?????? 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??????: Meeyou Carbide

【introduction】The construction of flexible electronic devices with certain functions and structures provides a variety of possibilities for human life in the future, such as wearable electronic products, implantable chips, sensing skin, flexible robots, and so on. With the deepening of the research on luminescent materials, these creative products are moving from the laboratory to people’s lives. For example, a clothing containing a light-emitting element, a detector built by an optical signal, a chip capable of releasing a drug through an optical signal, a chip that participates in a signal transmission, and the like. Early research, mainly using screen printing technology, to achieve a large-scale manufacturing of AC flexible luminescent materials. Nowadays, with the advent of 3D printing technology, flexible materials with more complex structures are also produced.The researchers have designed a novel structure of light-emitting devices, which are mainly composed of four parts, namely, a pair of parallel stack or side by side distribution of the electrode, light-emitting layer, dielectric layer and a controllable electrode layer. The control of the electrode layer is achieved by selecting a different polarizing material or an electroconductive thin film. This new structure is not only simple, but also conducive to large-scale manufacturing, more importantly, compared with the traditional sense of the light-emitting devices, a pair of opposing electrodes are no longer stacked with each other, but side by side distribution. It is because of this structural advantage, the researchers have designed different types of devices. For example, this flexible material is mounted on an umbrella, and when the water falls on an umbrella, the umbrella glows, which also makes it possible to build a remote detector that utilizes optical signal changes.Figure 1. Comparison of conventional sandwich configurations of light emitting devices (denoted as S-ELS) and polarized electrode bridge light emitting devices (denoted PEB-ELS)a) Schematic diagram of the structure of a conventional sandwich device (S-ELS)b) Schematic diagram of polarization electrode bridge light emitting device (PEB-ELS)c) Flexible display of PEB-ELS;d) The backside of the PEB-ELS is enlarged with an electrode width of 0.45 mm and a pitch of 0.40 mm.e) the water shines on the PEB-ELS;f) Comparison of changes in AC voltage before and after water dumping.Figure 2. Effect of bridging material, voltage and frequency on PEB-ELS performancea) PEB-ELS positive partial magnification, electrode width of 1.5 mm, spacing of 0.4 mm;b) the addition of different bridging liquid, the light in the dark situation;c) the relationship between the luminous intensity and the type and concentration of the bridged liquid at a voltage frequency of 2 kHz;d) the effect of substrate impedance on the luminous intensity, insert the picture shows the relationship between liquid contact time and luminous intensity;e) the relationship between the luminous intensity and the voltage frequency when the voltage is constant;f) Draw a Picasso painting on PEB-ELS with a pencil.Figure 3. Polarized electrode bridge experiment.a-b) bridging the experimental diagram, the first PEB-ELS is divided into two parts, and then use the hydrogel as a polarized bridge, the two parts connected to test;c) half of the PEB-ELS infiltrated in the two beakers;d) Transparent polyacrylamide hydrogel for bridging, 5 cm long, 1.6 cm wide, 0.3 cm thick;e) After the two beakers are connected with a hydrogel, the voltage is applied and the PEB-ELS emits light;f) Place the hydrogel directly on PEB-ELS and the material glows.Figure 4. Preparation and performance testing of rainwater sensorsa-b) rainwater sensor preparation diagram;c-d) rainwater sensor of the physical map, white and dark;e) hand as bridge electrode, PEB-ELS light;f) When the water is frozen, the emission intensity of PEB-ELS is weakened.【summary】This study presents a new, low-cost, flexible, light-emitting device that can be mass-produced. In this paper, the luminescence performance of the device is studied, and the relationship between the luminescence performance and the bridging material and the applied voltage is discussed. And then made it based on the optical signal sensor. When the umbrella is wet or touched by hand, the contact surface will light. Not only that, this new type of light emitting device can also be used to write, when writing with a pencil, the corresponding area can also light. This also provides a new possibility for the future development of touch display technology.
??????: Meeyou Carbide